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Multimolecular self-organization of acetylene and arylamines into 1-aryl-3-ethyl-4-vinylpyrroles in the KOBut/DMSO system

Elena Yur'evna Schmidt 1
Elena Yur'evna Schmidt
, 
Nadezhda Victorovna Semenova 1
Nadezhda Victorovna Semenova
, 
Elena V Ivanova 1
Elena V Ivanova
, 
Igor Alekseevich Ushakov 1
Igor Alekseevich Ushakov
, 
Boris Aleksandrovich Trofimov 1
Boris Aleksandrovich Trofimov
10.1016/j.mencom.2020.05.018
Published 2020-04-30
Communication , Volume 30, Issue 3, 315-317
11
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Schmidt E. Y. et al. Multimolecular self-organization of acetylene and arylamines into 1-aryl-3-ethyl-4-vinylpyrroles in the KOBut/DMSO system // Mendeleev Communications. 2020. Vol. 30. No. 3. pp. 315-317.
GOST all authors (up to 50) Copy
Schmidt E. Y., Semenova N. V., Ivanova E. V., Ushakov I. A., Trofimov B. A. Multimolecular self-organization of acetylene and arylamines into 1-aryl-3-ethyl-4-vinylpyrroles in the KOBut/DMSO system // Mendeleev Communications. 2020. Vol. 30. No. 3. pp. 315-317.
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TY - JOUR
DO - 10.1016/j.mencom.2020.05.018
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.05.018
TI - Multimolecular self-organization of acetylene and arylamines into 1-aryl-3-ethyl-4-vinylpyrroles in the KOBut/DMSO system
T2 - Mendeleev Communications
AU - Schmidt, Elena Yur'evna
AU - Semenova, Nadezhda Victorovna
AU - Ivanova, Elena V
AU - Ushakov, Igor Alekseevich
AU - Trofimov, Boris Aleksandrovich
PY - 2020
DA - 2020/04/30
PB - Mendeleev Communications
SP - 315-317
IS - 3
VL - 30
ER -
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@article{2020_Schmidt,
author = {Elena Yur'evna Schmidt and Nadezhda Victorovna Semenova and Elena V Ivanova and Igor Alekseevich Ushakov and Boris Aleksandrovich Trofimov},
title = {Multimolecular self-organization of acetylene and arylamines into 1-aryl-3-ethyl-4-vinylpyrroles in the KOBut/DMSO system},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.05.018},
number = {3},
pages = {315--317},
doi = {10.1016/j.mencom.2020.05.018}
}
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Schmidt, Elena Yur'evna, et al. “Multimolecular self-organization of acetylene and arylamines into 1-aryl-3-ethyl-4-vinylpyrroles in the KOBut/DMSO system.” Mendeleev Communications, vol. 30, no. 3, Apr. 2020, pp. 315-317. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.05.018.

Keywords

Acetylene
arylamines
nucleophilic addition
pyrroles
self-assemblies
superbases

Abstract

A new superbase-driven self-organization of four molecules of acetylene with one molecule of arylamine to 1-aryl-3ethyl-4-vinylpyrroles in the KOBut/DMSO system has been discovered. The process includes four acts of nucleophilic addition to acetylene followed by intramolecular cyclization of intermediate N,N-bis(1,3-dienyl)-N-arylamine.

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