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Efficient one-pot synthesis of diphenyl(pyrazin-2-yl)phosphine and its AgI, AuI and PtII complexes

Maxim Igorevich Rogovoy 1
Maxim Igorevich Rogovoy
, 
Maria Petrovna Davydova 1
Maria Petrovna Davydova
, 
Irina Yur'evna Bagryanskaya 2
Irina Yur'evna Bagryanskaya
, 
Alexandr Viktorovich Artem’ev 1
Alexandr Viktorovich Artem’ev
10.1016/j.mencom.2020.05.014
Published 2020-04-30
Communication , Volume 30, Issue 3, 305-307
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Rogovoy M. I. et al. Efficient one-pot synthesis of diphenyl(pyrazin-2-yl)phosphine and its AgI, AuI and PtII complexes // Mendeleev Communications. 2020. Vol. 30. No. 3. pp. 305-307.
GOST all authors (up to 50) Copy
Rogovoy M. I., Davydova M. P., Bagryanskaya I. Y., Artem’ev A. V. Efficient one-pot synthesis of diphenyl(pyrazin-2-yl)phosphine and its AgI, AuI and PtII complexes // Mendeleev Communications. 2020. Vol. 30. No. 3. pp. 305-307.
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TY - JOUR
DO - 10.1016/j.mencom.2020.05.014
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.05.014
TI - Efficient one-pot synthesis of diphenyl(pyrazin-2-yl)phosphine and its AgI, AuI and PtII complexes
T2 - Mendeleev Communications
AU - Rogovoy, Maxim Igorevich
AU - Davydova, Maria Petrovna
AU - Bagryanskaya, Irina Yur'evna
AU - Artem’ev, Alexandr Viktorovich
PY - 2020
DA - 2020/04/30
PB - Mendeleev Communications
SP - 305-307
IS - 3
VL - 30
ER -
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@article{2020_Rogovoy,
author = {Maxim Igorevich Rogovoy and Maria Petrovna Davydova and Irina Yur'evna Bagryanskaya and Alexandr Viktorovich Artem’ev},
title = {Efficient one-pot synthesis of diphenyl(pyrazin-2-yl)phosphine and its AgI, AuI and PtII complexes},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.05.014},
number = {3},
pages = {305--307},
doi = {10.1016/j.mencom.2020.05.014}
}
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Rogovoy, Maxim Igorevich, et al. “Efficient one-pot synthesis of diphenyl(pyrazin-2-yl)phosphine and its AgI, AuI and PtII complexes.” Mendeleev Communications, vol. 30, no. 3, Apr. 2020, pp. 305-307. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.05.014.

Keywords

diphenyl(pyrazin-2-yl)phosphine
gold(I) complexes
lithiation
platinum(II) complexes
pyrazine
silver(I) complexes
triphenylphosphine

Abstract

A convenient one-pot synthesis of diphenyl(pyrazin-2-yl)phosphine has been developed based on reaction of Ph3P with metallic lithium followed by treatment of the Ph2PLi formed with 2-chloropyrazine. The AgI, AuI and PtII chloride complexes derived from this phosphine have been synthesized and structurally characterized.

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