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Electrochemical and catalytic properties of nickel(II) complexes with bis(imino)acenaphthene and diazadiphosphacyclooctane ligands

Vera Vasil'evna Khrizanforova 1
Vera Vasil'evna Khrizanforova
, 
Robert Rustemovich Fayzullin 1
Robert Rustemovich Fayzullin
, 
Èlvira Ilgizovna Musina 1
Èlvira Ilgizovna Musina
, 
Andrey Anatol'evich Karasik 1
Andrey Anatol'evich Karasik
, 
10.1016/j.mencom.2020.05.013
Published 2020-04-30
Communication , Volume 30, Issue 3, 302-304
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Khrizanforova V. V. et al. Electrochemical and catalytic properties of nickel(II) complexes with bis(imino)acenaphthene and diazadiphosphacyclooctane ligands // Mendeleev Communications. 2020. Vol. 30. No. 3. pp. 302-304.
GOST all authors (up to 50) Copy
Khrizanforova V. V., Fayzullin R. R., Musina È. I., Karasik A. A., Budnikova Y. H. Electrochemical and catalytic properties of nickel(II) complexes with bis(imino)acenaphthene and diazadiphosphacyclooctane ligands // Mendeleev Communications. 2020. Vol. 30. No. 3. pp. 302-304.
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TY - JOUR
DO - 10.1016/j.mencom.2020.05.013
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.05.013
TI - Electrochemical and catalytic properties of nickel(II) complexes with bis(imino)acenaphthene and diazadiphosphacyclooctane ligands
T2 - Mendeleev Communications
AU - Khrizanforova, Vera Vasil'evna
AU - Fayzullin, Robert Rustemovich
AU - Musina, Èlvira Ilgizovna
AU - Karasik, Andrey Anatol'evich
AU - Budnikova, Yulia Hermanovna
PY - 2020
DA - 2020/04/30
PB - Mendeleev Communications
SP - 302-304
IS - 3
VL - 30
ER -
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@article{2020_Khrizanforova,
author = {Vera Vasil'evna Khrizanforova and Robert Rustemovich Fayzullin and Èlvira Ilgizovna Musina and Andrey Anatol'evich Karasik and Yulia Hermanovna Budnikova},
title = {Electrochemical and catalytic properties of nickel(II) complexes with bis(imino)acenaphthene and diazadiphosphacyclooctane ligands},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.05.013},
number = {3},
pages = {302--304},
doi = {10.1016/j.mencom.2020.05.013}
}
MLA
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Khrizanforova, Vera Vasil'evna, et al. “Electrochemical and catalytic properties of nickel(II) complexes with bis(imino)acenaphthene and diazadiphosphacyclooctane ligands.” Mendeleev Communications, vol. 30, no. 3, Apr. 2020, pp. 302-304. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.05.013.

Keywords

catalysis
electrochemistry
hydrogen
nickel complexes
phosphine
α-diimines

Abstract

The title complexes were prepared, and their redox and catalytic properties in hydrogen evolution reaction were examined. The catalytic current increases in the presence of a proton source near the potential of the nickel(I/0) couple for a mixture of nickel(II) complexes with different ligands. Moreover, the catalytic activity of mixed-ligand complexes in the hydrogen evolution reaction was higher than that of a bis-chelated diphosphine nickel(II) complex.

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