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Rare example of structurally characterized mononuclear N-heterocyclic carbene containing zinc carboxylate

Dmitriy Sergeyevich Yambulatov 1
Dmitriy Sergeyevich Yambulatov
, 
Pavel Alekseevich Petrov 2, 3
Pavel Alekseevich Petrov
, 
Yulia Vladimirovna Nelyubina 1, 4
Yulia Vladimirovna Nelyubina
, 
Alena Andreevna Starikova 5
Alena Andreevna Starikova
, 
Alexander Alexandrovich Pavlov 4
Alexander Alexandrovich Pavlov
, 
Dmitry Yuryevich Aleshin 4
Dmitry Yuryevich Aleshin
, 
Stanislav Alexandrovich Nikolaevskii 1
Stanislav Alexandrovich Nikolaevskii
, 
Mikhail Aleksandrovich Kiskin 1
Mikhail Aleksandrovich Kiskin
, 
Maksim Nail'evich Sokolov 2, 3
Maksim Nail'evich Sokolov
, 
Igor Leonidovich Eremenko 1, 4
Igor Leonidovich Eremenko
10.1016/j.mencom.2020.05.010
Published 2020-04-30
Communication , Volume 30, Issue 3, 293-295
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Yambulatov D. S. et al. Rare example of structurally characterized mononuclear N-heterocyclic carbene containing zinc carboxylate // Mendeleev Communications. 2020. Vol. 30. No. 3. pp. 293-295.
GOST all authors (up to 50) Copy
Yambulatov D. S., Petrov P. A., Nelyubina Y. V., Starikova A. A., Pavlov A. A., Aleshin D. Y., Nikolaevskii S. A., Kiskin M. A., Sokolov M. N., Eremenko I. L. Rare example of structurally characterized mononuclear N-heterocyclic carbene containing zinc carboxylate // Mendeleev Communications. 2020. Vol. 30. No. 3. pp. 293-295.
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TY - JOUR
DO - 10.1016/j.mencom.2020.05.010
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.05.010
TI - Rare example of structurally characterized mononuclear N-heterocyclic carbene containing zinc carboxylate
T2 - Mendeleev Communications
AU - Yambulatov, Dmitriy Sergeyevich
AU - Petrov, Pavel Alekseevich
AU - Nelyubina, Yulia Vladimirovna
AU - Starikova, Alena Andreevna
AU - Pavlov, Alexander Alexandrovich
AU - Aleshin, Dmitry Yuryevich
AU - Nikolaevskii, Stanislav Alexandrovich
AU - Kiskin, Mikhail Aleksandrovich
AU - Sokolov, Maksim Nail'evich
AU - Eremenko, Igor Leonidovich
PY - 2020
DA - 2020/04/30
PB - Mendeleev Communications
SP - 293-295
IS - 3
VL - 30
ER -
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@article{2020_Yambulatov,
author = {Dmitriy Sergeyevich Yambulatov and Pavel Alekseevich Petrov and Yulia Vladimirovna Nelyubina and Alena Andreevna Starikova and Alexander Alexandrovich Pavlov and Dmitry Yuryevich Aleshin and Stanislav Alexandrovich Nikolaevskii and Mikhail Aleksandrovich Kiskin and Maksim Nail'evich Sokolov and Igor Leonidovich Eremenko},
title = {Rare example of structurally characterized mononuclear N-heterocyclic carbene containing zinc carboxylate},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.05.010},
number = {3},
pages = {293--295},
doi = {10.1016/j.mencom.2020.05.010}
}
MLA
Cite this
MLA Copy
Yambulatov, Dmitriy Sergeyevich, et al. “Rare example of structurally characterized mononuclear N-heterocyclic carbene containing zinc carboxylate.” Mendeleev Communications, vol. 30, no. 3, Apr. 2020, pp. 293-295. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.05.010.

Keywords

carboxylate complexes
DFT calculations
N-heterocyclic carbenes
X-ray crystallography
zinc(II)

Abstract

An adduct of ZnII pivalate with N-heterocyclic carbene 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene has been prepared and characterized by X-ray diffraction analysis, NMR spectroscopy and DFT calculations. The compound preserves mononuclear structure in solution and does not switch the coordination mode from normal to abnormal.

References

1.
10.1016/j.mencom.2020.05.010_bib0005
N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis, 2011
2.
10.1016/j.mencom.2020.05.010_bib0010
N-Heterocyclic Carbenes: From Laboratory Curiosities to Efficient Synthetic Tools, 2017
3.
An overview of N-heterocyclic carbenes
Hopkinson M.N., Richter C., Schedler M., Glorius F.
Nature, 2014
4.
Ionic Pd/NHC Catalytic System Enables Recoverable Homogeneous Catalysis: Mechanistic Study and Application in the Mizoroki–Heck Reaction
Eremin D.B., Denisova E.A., Yu. Kostyukovich A., Martens J., Berden G., Oomens J., Khrustalev V.N., Chernyshev V.M., Ananikov V.P.
Chemistry - A European Journal, 2019
5.
Akmalov T.R., Masoud S.M., Petropavlovskikh D.A., Zotova M.A., Nefedov S.E., Osipov S.N.
Mendeleev Communications, 2018
6.
Akmalov T.R., Masoud S.M., Vorobyeva D.V., Dolgushin F.M., Nefedov S.E., Osipov S.N.
Mendeleev Communications, 2019
7.
NHC and nucleophile chelation effects on reactive iron(ii) species in alkyl–alkyl cross-coupling
Fleischauer V.E., Muñoz III S.B., Neate P.G., Brennessel W.W., Neidig M.L.
Chemical Science, 2018
8.
Reactions of CO2 with Heteroleptic Zinc and Zinc–NHC Complexes
Jochmann P., Stephan D.W.
Organometallics, 2013
9.
N-heterocyclic carbene complexes of Zn(II): synthesis, X-ray structures and reactivity
Wang D., Wurst K., Buchmeiser M.R.
Journal of Organometallic Chemistry, 2004
10.
Chemistry of Iron N-Heterocyclic Carbene Complexes: Syntheses, Structures, Reactivities, and Catalytic Applications
Riener K., Haslinger S., Raba A., Högerl M.P., Cokoja M., Herrmann W.A., Kühn F.E.
Chemical Reviews, 2014
12.
CO2 as a C1-building block for the catalytic methylation of amines
Jacquet O., Frogneux X., Das Neves Gomes C., Cantat T.
Chemical Science, 2013
14.
CO 2 , Magnesium, Aluminum, and Zinc Adducts of N‐Heterocyclic Carbenes as (Latent) Catalysts for Polyurethane Synthesis
Bantu B., Manohar Pawar G., Wurst K., Decker U., Schmidt A.M., Buchmeiser M.R.
European Journal of Inorganic Chemistry, 2009
15.
N‐Heterocyclic Carbene Based Tri‐organyl‐Zn–Alkyl Cations: Synthesis, Structures, and Use in CO 2 Functionalization
Specklin D., Fliedel C., Gourlaouen C., Bruyere J., Avilés T., Boudon C., Ruhlmann L., Dagorne S.
Chemistry - A European Journal, 2017
16.
Synthesis, structure, and thermal behavior of polymeric zinc(ii) pivalate
Fomina I.G., Chernyshev V.V., Velikodnyi Y.A., Bykov M.A., Malkerova I.P., Alikhanyan A.S., Zavorotnyi Y.S., Dobrokhotova Z.V., Eremenko I.L.
Russian Chemical Bulletin, 2013
18.
OLEX2: a complete structure solution, refinement and analysis program
Dolomanov O.V., Bourhis L.J., Gildea R.J., Howard J.A., Puschmann H.
Journal of Applied Crystallography, 2009
19.
SHELXT– Integrated space-group and crystal-structure determination
Sheldrick G.M.
Acta Crystallographica Section A: Foundations and Advances, 2015
20.
The anatomy of a comprehensive constrained, restrained refinement program for the modern computing environment –Olex2dissected
Bourhis L.J., Dolomanov O.V., Gildea R.J., Howard J.A., Puschmann H.
Acta Crystallographica Section A: Foundations and Advances, 2015
21.
Abnormal N-heterocyclic carbenes
Arnold P.L., Pearson S.
Coordination Chemistry Reviews, 2007
24.
Normal and Abnormal N-Heterocyclic Carbene Ligands
Albrecht M.
Advances in Organometallic Chemistry, 2014