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Nontrivial structural organization of pivalate complexes with the fragment {Fe2Li(μ3-O)}

, 
Mikhail Aleksandrovich Kiskin 1
Mikhail Aleksandrovich Kiskin
, 
Stanislav Alexandrovich Nikolaevskii 1
Stanislav Alexandrovich Nikolaevskii
,  , 
Petr Vital'evich Primakov 2, 3
Petr Vital'evich Primakov
, 
Alexander Sergeyevich Goloveshkin 2
Alexander Sergeyevich Goloveshkin
, 
Vladimir Konstantinovich Imshennik 4
Vladimir Konstantinovich Imshennik
, 
Yuri Vasilievich Maksimov 4
Yuri Vasilievich Maksimov
, 
Alexey Anatol'evich Sidorov 1
Alexey Anatol'evich Sidorov
, 
Igor Leonidovich Eremenko 1, 2
Igor Leonidovich Eremenko
10.1016/j.mencom.2020.05.003
Published 2020-04-30
Communication , Volume 30, Issue 3, 273-275
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Lutsenko I. A. et al. Nontrivial structural organization of pivalate complexes with the fragment {Fe2Li(μ3-O)} // Mendeleev Communications. 2020. Vol. 30. No. 3. pp. 273-275.
GOST all authors (up to 50) Copy
Lutsenko I. A., Kiskin M. A., Nikolaevskii S. A., Nelyubina Y. V., Primakov P. V., Goloveshkin A. S., Imshennik V. K., Maksimov Y. V., Sidorov A. A., Eremenko I. L. Nontrivial structural organization of pivalate complexes with the fragment {Fe2Li(μ3-O)} // Mendeleev Communications. 2020. Vol. 30. No. 3. pp. 273-275.
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TY - JOUR
DO - 10.1016/j.mencom.2020.05.003
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.05.003
TI - Nontrivial structural organization of pivalate complexes with the fragment {Fe2Li(μ3-O)}
T2 - Mendeleev Communications
AU - Lutsenko, Irina Aleksandrovna
AU - Kiskin, Mikhail Aleksandrovich
AU - Nikolaevskii, Stanislav Alexandrovich
AU - Nelyubina, Yulia Vladimirovna
AU - Primakov, Petr Vital'evich
AU - Goloveshkin, Alexander Sergeyevich
AU - Imshennik, Vladimir Konstantinovich
AU - Maksimov, Yuri Vasilievich
AU - Sidorov, Alexey Anatol'evich
AU - Eremenko, Igor Leonidovich
PY - 2020
DA - 2020/04/30
PB - Mendeleev Communications
SP - 273-275
IS - 3
VL - 30
ER -
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@article{2020_Lutsenko,
author = {Irina Aleksandrovna Lutsenko and Mikhail Aleksandrovich Kiskin and Stanislav Alexandrovich Nikolaevskii and Yulia Vladimirovna Nelyubina and Petr Vital'evich Primakov and Alexander Sergeyevich Goloveshkin and Vladimir Konstantinovich Imshennik and Yuri Vasilievich Maksimov and Alexey Anatol'evich Sidorov and Igor Leonidovich Eremenko},
title = {Nontrivial structural organization of pivalate complexes with the fragment {Fe2Li(μ3-O)}},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.05.003},
number = {3},
pages = {273--275},
doi = {10.1016/j.mencom.2020.05.003}
}
MLA
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MLA Copy
Lutsenko, Irina Aleksandrovna, et al. “Nontrivial structural organization of pivalate complexes with the fragment {Fe2Li(μ3-O)}.” Mendeleev Communications, vol. 30, no. 3, Apr. 2020, pp. 273-275. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.05.003.

Keywords

1,10-phenanthroline
crystal structure
heterometallic pivalate complexes
iron(III)
lithium
Mössbauer spectroscopy

Abstract

The reaction of FeIII and LII pivalates with 1,10-phenanthroline (phen) in toluene simultaneously gives the heteronuclear compounds [Fe2Li(O)(Piv)5(phen)2]·2HPiv and [{Li4(Piv)4(HPiv)2}{Fe2LiO(Piv)5(phen)2}2]·2PhMe with a structural organization uncharacteristic of FeIII and alkali metals. According to X-ray diffraction data, the trinuclear metal oxide moiety {Fe2Li (μ3-O)} forms two nonequivalent complex molecules, which form infinite horizontal chains in the crystal due to stacking interactions between aromatic rings.

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