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Radical anion and coordination compounds of polyconjugated molecules:potential organic materials with unusual magnetic, conducting and optical properties

Dmitry Valentinovich Konarev 1
Dmitry Valentinovich Konarev
10.1016/j.mencom.2020.05.001
Published 2020-04-30
Focus article , Volume 30, Issue 3, 249-261
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Konarev D. V. Radical anion and coordination compounds of polyconjugated molecules:potential organic materials with unusual magnetic, conducting and optical properties // Mendeleev Communications. 2020. Vol. 30. No. 3. pp. 249-261.
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Konarev D. V. Radical anion and coordination compounds of polyconjugated molecules:potential organic materials with unusual magnetic, conducting and optical properties // Mendeleev Communications. 2020. Vol. 30. No. 3. pp. 249-261.
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TY - JOUR
DO - 10.1016/j.mencom.2020.05.001
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.05.001
TI - Radical anion and coordination compounds of polyconjugated molecules:potential organic materials with unusual magnetic, conducting and optical properties
T2 - Mendeleev Communications
AU - Konarev, Dmitry Valentinovich
PY - 2020
DA - 2020/04/30
PB - Mendeleev Communications
SP - 249-261
IS - 3
VL - 30
ER -
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@article{2020_Konarev,
author = {Dmitry Valentinovich Konarev},
title = {Radical anion and coordination compounds of polyconjugated molecules:potential organic materials with unusual magnetic, conducting and optical properties},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.05.001},
number = {3},
pages = {249--261},
doi = {10.1016/j.mencom.2020.05.001}
}
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Konarev, Dmitry Valentinovich. “Radical anion and coordination compounds of polyconjugated molecules:potential organic materials with unusual magnetic, conducting and optical properties.” Mendeleev Communications, vol. 30, no. 3, Apr. 2020, pp. 249-261. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.05.001.
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Keywords

Charge transfer
charge transfer complex
fullerene
low dimension organic conductor
magnetic ordering of spins
organic electronics
phthalocyanine
porphyrin
radical anion salt
π-conjugated material

Abstract

Radical anion salts and coordination complexes of fullerenes, macrocycles and organic dyes obtained by reduction are considered. The reduction transfers an electron to these molecules enabling their participation in magnetic coupling of spins and/or high conductivity as well as modifies essentially their optical properties. Different types of electron transfer between the components have also been observed for these compounds. This review presents new approaches to the syntheses of these salts and complexes as well as their structural and physiochemical properties. Prospects for the development of this area are discussed.

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