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Copper(ii), cobalt(ii), manganese(ii) and nickel(ii) bis(hexafluoroacetylacetonate) complexes with N-vinylimidazole

Vladimir Ilyich Smirnov 1
Vladimir Ilyich Smirnov
, 
Lidia Mikhailovna Sinegovskaya 1
Lidia Mikhailovna Sinegovskaya
, 
Lidiya Nikiforovna Parshina 1
Lidiya Nikiforovna Parshina
, 
Alexandr Viktorovich Artem’ev 2, 3
Alexandr Viktorovich Artem’ev
, 
Irina Vladimirovna Sterkhova 1
Irina Vladimirovna Sterkhova
10.1016/j.mencom.2020.03.040
Published 2020-03-02
Communication , Volume 30, Issue 2, 246-248
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Smirnov V. I. et al. Copper(ii), cobalt(ii), manganese(ii) and nickel(ii) bis(hexafluoroacetylacetonate) complexes with N-vinylimidazole // Mendeleev Communications. 2020. Vol. 30. No. 2. pp. 246-248.
GOST all authors (up to 50) Copy
Smirnov V. I., Sinegovskaya L. M., Parshina L. N., Artem’ev A. V., Sterkhova I. V. Copper(ii), cobalt(ii), manganese(ii) and nickel(ii) bis(hexafluoroacetylacetonate) complexes with N-vinylimidazole // Mendeleev Communications. 2020. Vol. 30. No. 2. pp. 246-248.
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TY - JOUR
DO - 10.1016/j.mencom.2020.03.040
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.03.040
TI - Copper(ii), cobalt(ii), manganese(ii) and nickel(ii) bis(hexafluoroacetylacetonate) complexes with N-vinylimidazole
T2 - Mendeleev Communications
AU - Smirnov, Vladimir Ilyich
AU - Sinegovskaya, Lidia Mikhailovna
AU - Parshina, Lidiya Nikiforovna
AU - Artem’ev, Alexandr Viktorovich
AU - Sterkhova, Irina Vladimirovna
PY - 2020
DA - 2020/03/02
PB - Mendeleev Communications
SP - 246-248
IS - 2
VL - 30
ER -
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@article{2020_Smirnov,
author = {Vladimir Ilyich Smirnov and Lidia Mikhailovna Sinegovskaya and Lidiya Nikiforovna Parshina and Alexandr Viktorovich Artem’ev and Irina Vladimirovna Sterkhova},
title = {Copper(ii), cobalt(ii), manganese(ii) and nickel(ii) bis(hexafluoroacetylacetonate) complexes with N-vinylimidazole},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.03.040},
number = {2},
pages = {246--248},
doi = {10.1016/j.mencom.2020.03.040}
}
MLA
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Smirnov, Vladimir Ilyich, et al. “Copper(ii), cobalt(ii), manganese(ii) and nickel(ii) bis(hexafluoroacetylacetonate) complexes with N-vinylimidazole.” Mendeleev Communications, vol. 30, no. 2, Mar. 2020, pp. 246-248. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.03.040.

Keywords

crystal structure
hexafluoroacetylacetonates
metal complexes
UV-VIS spectra
X-ray

Abstract

Two new manganese(ii) and nickel(ii) bis(hexafluoroacetylacetonate) complexes with N-vinylimidazole were synthesized and characterized by single crystal X-ray diffraction analysis, UV-VIS and IR spectroscopy. Their structures were compared with those of related copper(ii) and cobalt(ii) complexes. In the case of copper complex, the coordination site formed by hexafluoroacetylacetonate at the Cu2+ ion and nitrogen atoms of the two vinylimidazole cycles is slightly distorted, while in all the other considered complexes, this distortion is insignificant.

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