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Unusual complexation of 1-phenylthiocarbamoyl-3-(pyridin-2-yl)pyrazoline with copper(ii) chloride

Nikolai Igorevich Vorozhtsov 1
Nikolai Igorevich Vorozhtsov
, 
Diana Dmitrievna Korablina 1
Diana Dmitrievna Korablina
, 
Lyudmila Alexandrovna Sviridova 1
Lyudmila Alexandrovna Sviridova
, 
Victor Aleksandrovich Tafeenko 1
Victor Aleksandrovich Tafeenko
, 
Anna Anisimovna Moiseeva 1
Anna Anisimovna Moiseeva
, 
Nikolai Vasil'evich Zyk 1
Nikolai Vasil'evich Zyk
, 
10.1016/j.mencom.2020.03.039
Published 2020-03-02
Communication , Volume 30, Issue 2, 244-245
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Vorozhtsov N. I. et al. Unusual complexation of 1-phenylthiocarbamoyl-3-(pyridin-2-yl)pyrazoline with copper(ii) chloride // Mendeleev Communications. 2020. Vol. 30. No. 2. pp. 244-245.
GOST all authors (up to 50) Copy
Vorozhtsov N. I., Korablina D. D., Sviridova L. A., Tafeenko V. A., Moiseeva A. A., Zyk N. V., Beloglazkina E. K. Unusual complexation of 1-phenylthiocarbamoyl-3-(pyridin-2-yl)pyrazoline with copper(ii) chloride // Mendeleev Communications. 2020. Vol. 30. No. 2. pp. 244-245.
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TY - JOUR
DO - 10.1016/j.mencom.2020.03.039
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.03.039
TI - Unusual complexation of 1-phenylthiocarbamoyl-3-(pyridin-2-yl)pyrazoline with copper(ii) chloride
T2 - Mendeleev Communications
AU - Vorozhtsov, Nikolai Igorevich
AU - Korablina, Diana Dmitrievna
AU - Sviridova, Lyudmila Alexandrovna
AU - Tafeenko, Victor Aleksandrovich
AU - Moiseeva, Anna Anisimovna
AU - Zyk, Nikolai Vasil'evich
AU - Beloglazkina, Elena Kimovna
PY - 2020
DA - 2020/03/02
PB - Mendeleev Communications
SP - 244-245
IS - 2
VL - 30
ER -
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@article{2020_Vorozhtsov,
author = {Nikolai Igorevich Vorozhtsov and Diana Dmitrievna Korablina and Lyudmila Alexandrovna Sviridova and Victor Aleksandrovich Tafeenko and Anna Anisimovna Moiseeva and Nikolai Vasil'evich Zyk and Elena Kimovna Beloglazkina},
title = {Unusual complexation of 1-phenylthiocarbamoyl-3-(pyridin-2-yl)pyrazoline with copper(ii) chloride},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.03.039},
number = {2},
pages = {244--245},
doi = {10.1016/j.mencom.2020.03.039}
}
MLA
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Vorozhtsov, Nikolai Igorevich, et al. “Unusual complexation of 1-phenylthiocarbamoyl-3-(pyridin-2-yl)pyrazoline with copper(ii) chloride.” Mendeleev Communications, vol. 30, no. 2, Mar. 2020, pp. 244-245. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.03.039.

Keywords

alcohols
copper(ii) complexes
pyrazolines
ring opening
thiosemicarbazone complexes
X-ray

Abstract

Complexation of 5-(4-dimethylaminophenyl)-1-phenylthiocarbamoyl-3-(pyridin-2-yl)-4,5-dihydro-1H-pyrazole with CuCl2 followed by recrystallization from alcohols as external nucleophiles affords the products of pyrazoline ring opening by thiosemicarbazone moiety. The structure of the obtained complex was confirmed by X-ray diffraction data.

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