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Electrocatalytic one-pot multicomponent assembly of aldehydes, 2,4-dihydro-3H-pyrazol-3-ones and kojic acid

, 
Anatoly Nikolaevich Vereshchagin 1
Anatoly Nikolaevich Vereshchagin
, 
Yuliya Evgenievna Ryzhkova 1
Yuliya Evgenievna Ryzhkova
, 
Stepan Konstantinovich Krymov 1, 2
Stepan Konstantinovich Krymov
, 
Natalia A Leonova 1, 2
Natalia A Leonova
, 
Alexander Sergeyevich Goloveshkin 3
Alexander Sergeyevich Goloveshkin
, 
Mikhail Petrovich Egorov 1
Mikhail Petrovich Egorov
10.1016/j.mencom.2020.03.031
Published 2020-03-02
Communication , Volume 30, Issue 2, 223-225
8
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Elinson M. N. et al. Electrocatalytic one-pot multicomponent assembly of aldehydes, 2,4-dihydro-3H-pyrazol-3-ones and kojic acid // Mendeleev Communications. 2020. Vol. 30. No. 2. pp. 223-225.
GOST all authors (up to 50) Copy
Elinson M. N., Vereshchagin A. N., Ryzhkova Y. E., Krymov S. K., Leonova N. A., Goloveshkin A. S., Egorov M. P. Electrocatalytic one-pot multicomponent assembly of aldehydes, 2,4-dihydro-3H-pyrazol-3-ones and kojic acid // Mendeleev Communications. 2020. Vol. 30. No. 2. pp. 223-225.
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TY - JOUR
DO - 10.1016/j.mencom.2020.03.031
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.03.031
TI - Electrocatalytic one-pot multicomponent assembly of aldehydes, 2,4-dihydro-3H-pyrazol-3-ones and kojic acid
T2 - Mendeleev Communications
AU - Elinson, Michail Nikolaevich
AU - Vereshchagin, Anatoly Nikolaevich
AU - Ryzhkova, Yuliya Evgenievna
AU - Krymov, Stepan Konstantinovich
AU - Leonova, Natalia A
AU - Goloveshkin, Alexander Sergeyevich
AU - Egorov, Mikhail Petrovich
PY - 2020
DA - 2020/03/02
PB - Mendeleev Communications
SP - 223-225
IS - 2
VL - 30
ER -
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@article{2020_Elinson,
author = {Michail Nikolaevich Elinson and Anatoly Nikolaevich Vereshchagin and Yuliya Evgenievna Ryzhkova and Stepan Konstantinovich Krymov and Natalia A Leonova and Alexander Sergeyevich Goloveshkin and Mikhail Petrovich Egorov},
title = {Electrocatalytic one-pot multicomponent assembly of aldehydes, 2,4-dihydro-3H-pyrazol-3-ones and kojic acid},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.03.031},
number = {2},
pages = {223--225},
doi = {10.1016/j.mencom.2020.03.031}
}
MLA
Cite this
MLA Copy
Elinson, Michail Nikolaevich, et al. “Electrocatalytic one-pot multicomponent assembly of aldehydes, 2,4-dihydro-3H-pyrazol-3-ones and kojic acid.” Mendeleev Communications, vol. 30, no. 2, Mar. 2020, pp. 223-225. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.03.031.

Keywords

2,4-dihydro-3H-pyrazol-3-one
aldehydes
electrocatalysis
kojic acid
multicomponent process
tandem reaction

Abstract

Electrocatalytic transformation of aldehydes, 2,4-dihydro-3H-pyrazol-3-ones and kojic acid in alcohols occurs in an undivided cell in the presence of sodium halides, selectively affording substituted 4-{[3-hydroxy-6-(hydroxymethyl)-4-oxo-4H-pyran-2-yl](aryl)methyl}-5-methyl-1,2-dihydro-3Hpyrazol-3-ones in 73–95% yields and with 240–320% current efficiency. The multicomponent process provides a facile and efficient way to the new type of systems with heterocyclic moieties separated by aryl-substituted C-spacer. The product structure has been confirmed by X-ray diffraction data

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