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Mono- and binuclear chloride complexes of bismuth(iii) with 2-aminopyrimidine cations depending on specific synthetic route

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Trofimova T. P. et al. Mono- and binuclear chloride complexes of bismuth(iii) with 2-aminopyrimidine cations depending on specific synthetic route // Mendeleev Communications. 2020. Vol. 30. No. 2. pp. 202-204.
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Trofimova T. P., Orlova M. A., Tafeenko V. A., Proshin A. N., Glazkova I. S., Pankratov D. A. Mono- and binuclear chloride complexes of bismuth(iii) with 2-aminopyrimidine cations depending on specific synthetic route // Mendeleev Communications. 2020. Vol. 30. No. 2. pp. 202-204.
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TY - JOUR
DO - 10.1016/j.mencom.2020.03.024
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.03.024
TI - Mono- and binuclear chloride complexes of bismuth(iii) with 2-aminopyrimidine cations depending on specific synthetic route
T2 - Mendeleev Communications
AU - Trofimova, Tatiana Petrovna
AU - Orlova, Marina Alekseevna
AU - Tafeenko, Victor Aleksandrovich
AU - Proshin, Alexey N
AU - Glazkova, Iana Sergeevna
AU - Pankratov, Denis A
PY - 2020
DA - 2020/03/02
PB - Mendeleev Communications
SP - 202-204
IS - 2
VL - 30
ER -
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@article{2020_Trofimova,
author = {Tatiana Petrovna Trofimova and Marina Alekseevna Orlova and Victor Aleksandrovich Tafeenko and Alexey N Proshin and Iana Sergeevna Glazkova and Denis A Pankratov},
title = {Mono- and binuclear chloride complexes of bismuth(iii) with 2-aminopyrimidine cations depending on specific synthetic route},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.03.024},
number = {2},
pages = {202--204},
doi = {10.1016/j.mencom.2020.03.024}
}
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Trofimova, Tatiana Petrovna, et al. “Mono- and binuclear chloride complexes of bismuth(iii) with 2-aminopyrimidine cations depending on specific synthetic route.” Mendeleev Communications, vol. 30, no. 2, Mar. 2020, pp. 202-204. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.03.024.

Keywords

2-aminopyrimidine
bismuth(iii) complexes
MTT-assay
X-ray crystallography
XRD-method

Abstract

Complexes of Biiii with 2-aminopyrimidine cations with metal-to-ligand ratios of 1:3 or 2:4 (depending on reaction conditions) were synthesized and characterized by elemental analysis, 1H NMR spectroscopy, and single crystal X-ray crystallography. The possibility of conversion of the latter complex into the former one was demonstrated. The determined cytotoxicity depended on the structure of these complexes.

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