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Synthesis and properties of the salts of 1-nitropropan-2-one and 1-nitrobutan-2-one

Vladimir Leonidovich Rusinov 1, 2
Vladimir Leonidovich Rusinov
, 
Roman Alexandrovich Drokin 1
Roman Alexandrovich Drokin
, 
Dmitrii V Tiufiakov 1
Dmitrii V Tiufiakov
, 
Egor Konstantinovich Voinkov 1
Egor Konstantinovich Voinkov
, 
Eugeny Nartsissovich Ulomsky 1, 2
Eugeny Nartsissovich Ulomsky
10.1016/j.mencom.2020.03.015
Published 2020-03-02
Communication , Volume 30, Issue 2, 177-179
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Rusinov V. L. et al. Synthesis and properties of the salts of 1-nitropropan-2-one and 1-nitrobutan-2-one // Mendeleev Communications. 2020. Vol. 30. No. 2. pp. 177-179.
GOST all authors (up to 50) Copy
Rusinov V. L., Drokin R. A., Tiufiakov D. V., Voinkov E. K., Ulomsky E. N. Synthesis and properties of the salts of 1-nitropropan-2-one and 1-nitrobutan-2-one // Mendeleev Communications. 2020. Vol. 30. No. 2. pp. 177-179.
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TY - JOUR
DO - 10.1016/j.mencom.2020.03.015
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.03.015
TI - Synthesis and properties of the salts of 1-nitropropan-2-one and 1-nitrobutan-2-one
T2 - Mendeleev Communications
AU - Rusinov, Vladimir Leonidovich
AU - Drokin, Roman Alexandrovich
AU - Tiufiakov, Dmitrii V
AU - Voinkov, Egor Konstantinovich
AU - Ulomsky, Eugeny Nartsissovich
PY - 2020
DA - 2020/03/02
PB - Mendeleev Communications
SP - 177-179
IS - 2
VL - 30
ER -
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@article{2020_Rusinov,
author = {Vladimir Leonidovich Rusinov and Roman Alexandrovich Drokin and Dmitrii V Tiufiakov and Egor Konstantinovich Voinkov and Eugeny Nartsissovich Ulomsky},
title = {Synthesis and properties of the salts of 1-nitropropan-2-one and 1-nitrobutan-2-one},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.03.015},
number = {2},
pages = {177--179},
doi = {10.1016/j.mencom.2020.03.015}
}
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Rusinov, Vladimir Leonidovich, et al. “Synthesis and properties of the salts of 1-nitropropan-2-one and 1-nitrobutan-2-one.” Mendeleev Communications, vol. 30, no. 2, Mar. 2020, pp. 177-179. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.03.015.

Keywords

diazonium salts
enamines
hydrazones
Ketones
nitro compounds
nitroacetone
nitroazine systems
pyrimidinones

Abstract

A new safe synthesis of α-nitro ketone salts via alkaline hydrolysis of 2-morpholino-1-nitroalkenes has been developed. The salts were introduced into the reactions of diazotization and heterocyclization. Crystal structures of new 2-morpholino-1-nitrobut-1-ene and 6-ethyl-5-nitro-4phenyl-3,4-dihydropyrimidin-2-one have been determined.

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