Keywords
brushite
crazing
Nanocomposite
phosphates
polylactide
porous matrix
struvite
uniaxial tension
Abstract
Experimental conditions have been established for the preparation of stable open-pore matrices with pore diameters of 10–20nm on the basis of semicrystalline polylactide films by thedelocalized crazing mechanism. The synthesis of phosphates of calcium (brushite) and magnesium (struvite) in the pores of such a polymer matrix allows one to tune the size of the formed crystallites, which has appeared to be about 30nm, and to obtain nanocomposites with high dispersity of the components. The resulting nanocomposites were characterized by SAXS, SEM, TGA and XRD methods.
References
1.
Okamoto M., John B.
Progress in Polymer Science,
2013
2.
Neumann M., Epple M.
European Journal of Trauma,
2006
3.
Kang Z., Zhang X., Chen Y., Akram M.Y., Nie J., Zhu X.
Materials Science and Engineering C,
2016
4.
Goldberg M.A., Smirnov V.V., Antonova O.S., Khairutdinova D.R., Smirnov S.V., Krylov A.I., Sergeeva N.S., Sviridova I.K., Kirsanova V.A., Akhmedova S.A., Zhevnenko S.N., Barinov S.M.
Mendeleev Communications,
2018
5.
10.1016/j.mencom.2020.03.013_bib0025
Currey
Bones: Structure and Mechanics,
2002
6.
Egiazaryan T.A., Makarov V.M., Moskalev M.V., Razborov D.A., Fedushkin I.L.
Mendeleev Communications,
2019
7.
Zuev D.M., Klimashina E.S., Evdokimov P.V., Filippov Y.Y., Putlyaev V.I.
Inorganic Materials,
2018
8.
Zhou H., Lawrence J.G., Bhaduri S.B.
Acta Biomaterialia,
2012
9.
Nifant’ev I.E., Shlyakhtin A.V., Bagrov V.V., Komarov P.D., Tavtorkin A.N., Minyaev M.E., Ivchenko P.V.
Mendeleev Communications,
2018
10.
10.1016/j.mencom.2020.03.013_bib0050
Nainar
Regenerative Research,
2012
11.
Li J., X.L.Lu, Zheng Y.F.
Applied Surface Science,
2008
12.
10.1016/j.mencom.2020.03.013_bib0060
Volynskii
Surface Phenomena in the Structural and Mechanical Behaviour of Solid Polymers,
2016
13.
Trofimchuk E.S., Efimov A.V., Grokhovskaya T.E., Nikonorova N.I., Moskvina M.A., Sedush N.G., Dorovatovskii P.V., Ivanova O.A., Rukhlya E.G., Volynskii A.L., Chvalun S.N.
ACS applied materials & interfaces,
2017
14.
Trofimchuk E.S., Efimov A.V., Moskvina M.A., Ivanova O.A., Nikonorova N.I., Zezin S.B., Bakirov A.V., Volynskii A.L.
Polymer Science - Series A,
2018
15.
Fadeeva I.V., Trofimchuk E.S., Giretova M., Mal’tsev D.K., Nikonorova N.I., Fomin A.S., Rau J.V., Medvecky L., Barinov S.M.
Biomedical Physics and Engineering Express,
2015
16.
Dudnik A.O., Trofimchuk E.S., Efimov A.V., Nikonorova N.I., Rukhlya E.G., Nikitin L.N., Yaminsky I.V., Volynskii A.L.
Macromolecules,
2018
17.
Efimova A.A., Grokhovskaya T.E., Efimov A.V.
Mendeleev Communications,
2017
18.
Yarysheva A.Y., Bagrov D.V., Bakirov A.V., Yarysheva L.M., Chvalun S.N., Volynskii A.L.
European Polymer Journal,
2018
19.
Swanson H.E., McMurdie H.F., Morris M.C., Evans E.H.
2015
20.
Duff E.J.
Journal of Applied Chemistry and Biotechnology,
2007
21.
Ramlogan M.V., Rouff A.A.
Journal of Thermal Analysis and Calorimetry,
2015