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A panchromatic pyrazine-fused porphyrin dimer

Inna Alievna Abdulaeva 1
Inna Alievna Abdulaeva
, 
Daria Andreevna Polivanovskaia 1
Daria Andreevna Polivanovskaia
, 
Kirill Petrovich Birin 1
Kirill Petrovich Birin
, 
Yulia Germanovna Gorbunova 1, 2
Yulia Germanovna Gorbunova
, 
Aslan Yusupovich Tsivadze 1, 2
Aslan Yusupovich Tsivadze
10.1016/j.mencom.2020.03.010
Published 2020-03-02
Communication , Volume 30, Issue 2, 162-164
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Abdulaeva I. A. et al. A panchromatic pyrazine-fused porphyrin dimer // Mendeleev Communications. 2020. Vol. 30. No. 2. pp. 162-164.
GOST all authors (up to 50) Copy
Abdulaeva I. A., Polivanovskaia D. A., Birin K. P., Gorbunova Y. G., Tsivadze A. Y. A panchromatic pyrazine-fused porphyrin dimer // Mendeleev Communications. 2020. Vol. 30. No. 2. pp. 162-164.
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TY - JOUR
DO - 10.1016/j.mencom.2020.03.010
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.03.010
TI - A panchromatic pyrazine-fused porphyrin dimer
T2 - Mendeleev Communications
AU - Abdulaeva, Inna Alievna
AU - Polivanovskaia, Daria Andreevna
AU - Birin, Kirill Petrovich
AU - Gorbunova, Yulia Germanovna
AU - Tsivadze, Aslan Yusupovich
PY - 2020
DA - 2020/03/02
PB - Mendeleev Communications
SP - 162-164
IS - 2
VL - 30
ER -
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@article{2020_Abdulaeva,
author = {Inna Alievna Abdulaeva and Daria Andreevna Polivanovskaia and Kirill Petrovich Birin and Yulia Germanovna Gorbunova and Aslan Yusupovich Tsivadze},
title = {A panchromatic pyrazine-fused porphyrin dimer},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.03.010},
number = {2},
pages = {162--164},
doi = {10.1016/j.mencom.2020.03.010}
}
MLA
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MLA Copy
Abdulaeva, Inna Alievna, et al. “A panchromatic pyrazine-fused porphyrin dimer.” Mendeleev Communications, vol. 30, no. 2, Mar. 2020, pp. 162-164. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.03.010.

Keywords

diamines
nickel complexes
oxidation
panchromatic absorption
porphyrins
pyrazine-fused dimers

Abstract

New pyrazine-fused porphyrin dimer was unexpectedly produced by mild oxidation of [2,3-diamino-5,10,15,20-tetrakis(4-butoxyphenyl)porphyrinato]nickel(ii) in 40% yield. The obtained porphyrin dimer demonstrates bathochromic shift of absorption bands compared to the reported analogues, along with panchromatic absorption in the 250–650nm range, which is promising for optical, photovoltaic and medical applications.

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