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Synthesis and crystal structure of the first amino-1,3a,4,6a-tetraazapentalenes

Alexey Anatol'evich Konnov 1
Alexey Anatol'evich Konnov
,  , 
Aleksandr Mikhailovich Churakov 1
Aleksandr Mikhailovich Churakov
, 
Yurii Andreevich Strelenko 1
Yurii Andreevich Strelenko
, 
Konstantin Alexandrovich Lyssenko 2
Konstantin Alexandrovich Lyssenko
, 
Vladimir Alexandrovich Tartakovsky 1
Vladimir Alexandrovich Tartakovsky
10.1016/j.mencom.2020.03.002
Published 2020-03-02
Communication , Volume 30, Issue 2, 139-141
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Konnov A. A. et al. Synthesis and crystal structure of the first amino-1,3a,4,6a-tetraazapentalenes // Mendeleev Communications. 2020. Vol. 30. No. 2. pp. 139-141.
GOST all authors (up to 50) Copy
Konnov A. A., Klenov M. S., Churakov A. M., Strelenko Y. A., Lyssenko K. A., Tartakovsky V. A. Synthesis and crystal structure of the first amino-1,3a,4,6a-tetraazapentalenes // Mendeleev Communications. 2020. Vol. 30. No. 2. pp. 139-141.
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TY - JOUR
DO - 10.1016/j.mencom.2020.03.002
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.03.002
TI - Synthesis and crystal structure of the first amino-1,3a,4,6a-tetraazapentalenes
T2 - Mendeleev Communications
AU - Konnov, Alexey Anatol'evich
AU - Klenov, Michael Sergeevich
AU - Churakov, Aleksandr Mikhailovich
AU - Strelenko, Yurii Andreevich
AU - Lyssenko, Konstantin Alexandrovich
AU - Tartakovsky, Vladimir Alexandrovich
PY - 2020
DA - 2020/03/02
PB - Mendeleev Communications
SP - 139-141
IS - 2
VL - 30
ER -
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@article{2020_Konnov,
author = {Alexey Anatol'evich Konnov and Michael Sergeevich Klenov and Aleksandr Mikhailovich Churakov and Yurii Andreevich Strelenko and Konstantin Alexandrovich Lyssenko and Vladimir Alexandrovich Tartakovsky},
title = {Synthesis and crystal structure of the first amino-1,3a,4,6a-tetraazapentalenes},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.03.002},
number = {2},
pages = {139--141},
doi = {10.1016/j.mencom.2020.03.002}
}
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Konnov, Alexey Anatol'evich, et al. “Synthesis and crystal structure of the first amino-1,3a,4,6a-tetraazapentalenes.” Mendeleev Communications, vol. 30, no. 2, Mar. 2020, pp. 139-141. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.03.002.

Keywords

1,2,3-triazoles
azides
Cyclization
differential scanning calorimetry
tetraazapentalenes
X-ray

Abstract

Synthesis of the first amino- and formylamino-1,3a,4,6atetraazapentalenes via thermolysis of the corresponding 4-amino- and 4-formylamino-2-(2-azidophenyl)-2H-[1,2,3]triazoles has been elaborated. The crystal structures of 2-amino-3-(tert-butyl-NNO-azoxy)-1H-[1,2,3]triazolo[2,1-a][1,2,3]benzotriazol-1-id-4-ium and 3-amino-2-(tert-butyl-NNO-azoxy)-1H-[1,2,3]triazolo[2,1-a][1,2,3]benzotriazol-1-id4-ium have been established using X-ray diffraction analysis.

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