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Alkyl formates as reagents for reductive amination of carbonyl compounds

, 
Ilia Romanovich Cherkashchenko 2
Ilia Romanovich Cherkashchenko
, 
Anton Kuznetsov 3
Anton Kuznetsov
, 
Fedor Vsevolodovich Kliuev 3
Fedor Vsevolodovich Kliuev
, 
Sergey Semenov 3
Sergey Semenov
,  , 
Gleb Leonidovich Denisov 1
Gleb Leonidovich Denisov
, 
Denis Alexandrovich Chusov 1, 5
Denis Alexandrovich Chusov
10.1016/j.mencom.2020.01.037
Published 2019-12-30
Communication , Volume 30, Issue 1, 112-113
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Afanasyev O. I. et al. Alkyl formates as reagents for reductive amination of carbonyl compounds // Mendeleev Communications. 2019. Vol. 30. No. 1. pp. 112-113.
GOST all authors (up to 50) Copy
Afanasyev O. I., Cherkashchenko I. R., Kuznetsov A., Kliuev F. V., Semenov S., Chusova O. G., Denisov G. L., Chusov D. A. Alkyl formates as reagents for reductive amination of carbonyl compounds // Mendeleev Communications. 2019. Vol. 30. No. 1. pp. 112-113.
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TY - JOUR
DO - 10.1016/j.mencom.2020.01.037
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.01.037
TI - Alkyl formates as reagents for reductive amination of carbonyl compounds
T2 - Mendeleev Communications
AU - Afanasyev, Oleg Ilyich
AU - Cherkashchenko, Ilia Romanovich
AU - Kuznetsov, Anton
AU - Kliuev, Fedor Vsevolodovich
AU - Semenov, Sergey
AU - Chusova, Olga Gennad'evna
AU - Denisov, Gleb Leonidovich
AU - Chusov, Denis Alexandrovich
PY - 2019
DA - 2019/12/30
PB - Mendeleev Communications
SP - 112-113
IS - 1
VL - 30
ER -
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@article{2019_Afanasyev,
author = {Oleg Ilyich Afanasyev and Ilia Romanovich Cherkashchenko and Anton Kuznetsov and Fedor Vsevolodovich Kliuev and Sergey Semenov and Olga Gennad'evna Chusova and Gleb Leonidovich Denisov and Denis Alexandrovich Chusov},
title = {Alkyl formates as reagents for reductive amination of carbonyl compounds},
journal = {Mendeleev Communications},
year = {2019},
volume = {30},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.01.037},
number = {1},
pages = {112--113},
doi = {10.1016/j.mencom.2020.01.037}
}
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Cite this
MLA Copy
Afanasyev, Oleg Ilyich, et al. “Alkyl formates as reagents for reductive amination of carbonyl compounds.” Mendeleev Communications, vol. 30, no. 1, Dec. 2019, pp. 112-113. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.01.037.

Keywords

carbon monoxide surrogates
formic acid esters
reduction
reductive amination
rhodium.

Abstract

Alkyl formates in the presence of basic additives can serve as a reagent in the direct reductive amination of carbonyl compounds. The developed procedure can be applied to various aldehydes and ketones with electron donating and electron withdrawing groups.

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