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Crystal structure and conformational diversity of fluorinated alkyl tosylates

Dmitry Evgen'evich Arkhipov 1
Dmitry Evgen'evich Arkhipov
, 
Alexander Victorovich Lyubeshkin 2
Alexander Victorovich Lyubeshkin
, 
Alexander Dmitrievich Volodin 1
Alexander Dmitrievich Volodin
, 
Alexander Aleksandrovich Korlyukov 1
Alexander Aleksandrovich Korlyukov
10.1016/j.mencom.2020.01.034
Published 2019-12-30
Communication , Volume 30, Issue 1, 103-105
2
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Arkhipov D. E. et al. Crystal structure and conformational diversity of fluorinated alkyl tosylates // Mendeleev Communications. 2019. Vol. 30. No. 1. pp. 103-105.
GOST all authors (up to 50) Copy
Arkhipov D. E., Lyubeshkin A. V., Volodin A. D., Korlyukov A. A. Crystal structure and conformational diversity of fluorinated alkyl tosylates // Mendeleev Communications. 2019. Vol. 30. No. 1. pp. 103-105.
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TY - JOUR
DO - 10.1016/j.mencom.2020.01.034
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.01.034
TI - Crystal structure and conformational diversity of fluorinated alkyl tosylates
T2 - Mendeleev Communications
AU - Arkhipov, Dmitry Evgen'evich
AU - Lyubeshkin, Alexander Victorovich
AU - Volodin, Alexander Dmitrievich
AU - Korlyukov, Alexander Aleksandrovich
PY - 2019
DA - 2019/12/30
PB - Mendeleev Communications
SP - 103-105
IS - 1
VL - 30
ER -
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@article{2019_Arkhipov,
author = {Dmitry Evgen'evich Arkhipov and Alexander Victorovich Lyubeshkin and Alexander Dmitrievich Volodin and Alexander Aleksandrovich Korlyukov},
title = {Crystal structure and conformational diversity of fluorinated alkyl tosylates},
journal = {Mendeleev Communications},
year = {2019},
volume = {30},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.01.034},
number = {1},
pages = {103--105},
doi = {10.1016/j.mencom.2020.01.034}
}
MLA
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MLA Copy
Arkhipov, Dmitry Evgen'evich, et al. “Crystal structure and conformational diversity of fluorinated alkyl tosylates.” Mendeleev Communications, vol. 30, no. 1, Dec. 2019, pp. 103-105. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.01.034.

Keywords

intra- and intermolecular interactions.
organofluorine compounds
quantum chemical calculations
tosylate derivatives
X-ray studies

Abstract

Crystal structures of fluorinated alkyl tosylates TsOCH2CF2CHFCF3 and TsOCH2(CF2)3CHF2 have been characterized by X-ray diffraction and quantum chemical calculations. The calculations have revealed the stabilization of head-to-tail conformation for TsOCH2CHFCF2CF3 due to intramolecular F・・・p and C–H・・・π interactions. Alternatively, for TsOCH2(CF2)3CHF2 these interactions cannot be responsible for the stabilization of head-to-tail conformation, thus the linear conformation is proved to be more stable.

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