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Synthesis and structures of two mononuclear iron(ii) complexes derived from polypyridine ligands

Hongqiao Wang 1, 2
Hongqiao Wang
, 
Nan Wu 1
Nan Wu
, 
Jing Zheng 1
Jing Zheng
, 
Chunyang Zheng 1, 2
Chunyang Zheng
, 
Dunjia Wang 1
Dunjia Wang
1 Hubei Key Laboratory of Pollutant Analysis and Reuse Technology, Hubei Normal University, Huangshi, P.R. China
2 Department of Chemistry, The School of Art and Science of Hubei Normal University, Huangshi, P.R. China
10.1016/j.mencom.2020.01.033
Published 2019-12-30
Communication , Volume 30, Issue 1, 100-102
3
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Wang H. et al. Synthesis and structures of two mononuclear iron(ii) complexes derived from polypyridine ligands // Mendeleev Communications. 2019. Vol. 30. No. 1. pp. 100-102.
GOST all authors (up to 50) Copy
Wang H., Wu N., Zheng J., Zheng C., Wang D. Synthesis and structures of two mononuclear iron(ii) complexes derived from polypyridine ligands // Mendeleev Communications. 2019. Vol. 30. No. 1. pp. 100-102.
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TY - JOUR
DO - 10.1016/j.mencom.2020.01.033
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.01.033
TI - Synthesis and structures of two mononuclear iron(ii) complexes derived from polypyridine ligands
T2 - Mendeleev Communications
AU - Wang, Hongqiao
AU - Wu, Nan
AU - Zheng, Jing
AU - Zheng, Chunyang
AU - Wang, Dunjia
PY - 2019
DA - 2019/12/30
PB - Mendeleev Communications
SP - 100-102
IS - 1
VL - 30
ER -
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@article{2019_Wang,
author = {Hongqiao Wang and Nan Wu and Jing Zheng and Chunyang Zheng and Dunjia Wang},
title = {Synthesis and structures of two mononuclear iron(ii) complexes derived from polypyridine ligands},
journal = {Mendeleev Communications},
year = {2019},
volume = {30},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.01.033},
number = {1},
pages = {100--102},
doi = {10.1016/j.mencom.2020.01.033}
}
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Wang, Hongqiao, et al. “Synthesis and structures of two mononuclear iron(ii) complexes derived from polypyridine ligands.” Mendeleev Communications, vol. 30, no. 1, Dec. 2019, pp. 100-102. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.01.033.
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Keywords

low-spin
metal complexes
one-pot synthesis
polypyridine

Abstract

Three polypyridine ligands such as tri(2-pyridyl)methane, (2,2’-bipyridin-6-yl)di(2-pyridyl)methane and 2,6-bis[di(2-pyridyl)methyl] pyridine as well as their new iron(II) mononuclear complexes have been obtained in a one-pot synthesis. Detailed structural analyses and magnetic susceptibility measurements confirm the expected six-coordinate octahedral geometry and the metric parameters are consistent with lowspin iron(II) in the complexes.

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