Home / Publications / One-step synthesis of new aluminum hydrides bearing a highly sterically hindered acenaphthene-1,2-diimine ligand

One-step synthesis of new aluminum hydrides bearing a highly sterically hindered acenaphthene-1,2-diimine ligand

Mikhail Vladimirovich Moskalev 1
Mikhail Vladimirovich Moskalev
, 
Danila Aleksandrovich Razborov 1
Danila Aleksandrovich Razborov
, 
Andrey Andreevich Bazanov 1
Andrey Andreevich Bazanov
, 
Vladimir Gennad'evich Sokolov 1
Vladimir Gennad'evich Sokolov
, 
Tatyana Sergeevna Koptseva 1
Tatyana Sergeevna Koptseva
, 
Eugeny Vladimirovich Baranov 1
Eugeny Vladimirovich Baranov
, 
Igor Leonidovich Fedushkin 1
Igor Leonidovich Fedushkin
10.1016/j.mencom.2020.01.031
Published 2019-12-30
Communication , Volume 30, Issue 1, 94-96
16
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Moskalev M. V. et al. One-step synthesis of new aluminum hydrides bearing a highly sterically hindered acenaphthene-1,2-diimine ligand // Mendeleev Communications. 2019. Vol. 30. No. 1. pp. 94-96.
GOST all authors (up to 50) Copy
Moskalev M. V., Razborov D. A., Bazanov A. A., Sokolov V. G., Koptseva T. S., Baranov E. V., Fedushkin I. L. One-step synthesis of new aluminum hydrides bearing a highly sterically hindered acenaphthene-1,2-diimine ligand // Mendeleev Communications. 2019. Vol. 30. No. 1. pp. 94-96.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2020.01.031
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.01.031
TI - One-step synthesis of new aluminum hydrides bearing a highly sterically hindered acenaphthene-1,2-diimine ligand
T2 - Mendeleev Communications
AU - Moskalev, Mikhail Vladimirovich
AU - Razborov, Danila Aleksandrovich
AU - Bazanov, Andrey Andreevich
AU - Sokolov, Vladimir Gennad'evich
AU - Koptseva, Tatyana Sergeevna
AU - Baranov, Eugeny Vladimirovich
AU - Fedushkin, Igor Leonidovich
PY - 2019
DA - 2019/12/30
PB - Mendeleev Communications
SP - 94-96
IS - 1
VL - 30
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2019_Moskalev,
author = {Mikhail Vladimirovich Moskalev and Danila Aleksandrovich Razborov and Andrey Andreevich Bazanov and Vladimir Gennad'evich Sokolov and Tatyana Sergeevna Koptseva and Eugeny Vladimirovich Baranov and Igor Leonidovich Fedushkin},
title = {One-step synthesis of new aluminum hydrides bearing a highly sterically hindered acenaphthene-1,2-diimine ligand},
journal = {Mendeleev Communications},
year = {2019},
volume = {30},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.01.031},
number = {1},
pages = {94--96},
doi = {10.1016/j.mencom.2020.01.031}
}
MLA
Cite this
MLA Copy
Moskalev, Mikhail Vladimirovich, et al. “One-step synthesis of new aluminum hydrides bearing a highly sterically hindered acenaphthene-1,2-diimine ligand.” Mendeleev Communications, vol. 30, no. 1, Dec. 2019, pp. 94-96. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.01.031.

Keywords

acenaphthenes
aluminum hydrides
diimine ligands
imines
redox-active ligands
sterically hindered ligands

Abstract

Treatment of a bulky dbhmp-bian ligand (dbhmp-bian==1,2-bis[(2,6-dibenzhydryl-4-methylphenyl)imino]acenaphthene) by 1 equiv. of LiAlH4 or mixture of 3/4 equiv. LiAlH4 and 1/3 eqiuv. AlCl3 in tetrahydrofuran results in new hydrides [(dbhmp-bian)AlH2(THF)]-[Li(THF)4]+ and (dbhmp-bian)AlH(THF), respectively. Both complexes were characterized by spectroscopic (IR, NMR) and X-ray diffraction methods.

References

2.
Soluble aluminum hydrides function as catalysts in deprotonation, insertion, and activation reactions
Li W., Ma X., Walawalkar M.G., Yang Z., Roesky H.W.
Coordination Chemistry Reviews, 2017
5.
Reaction of sterically encumbered phenols, TEMPO-H, and organocarbonyl insertion reactions with L-AlH2 (L = HC(MeCNDipp)2, Dipp = 2,6-diisopropylphenyl)
Keyes L.K., Todd A.D., Giffin N.A., Veinot A.J., Hendsbee A.D., Robertson K.N., Geier S.J., Masuda J.D.
RSC Advances, 2017
10.
Hydroalumination of Carbon Dioxide, Carbon Disulfide, and Phenyl Isocyanate with an Aluminum Ketiminate Compound
Kuo P., Chen I., Chang J., Lee M., Hu C., Hung C., Lee H., Huang J.
European Journal of Inorganic Chemistry, 2004
11.
An Aluminum Dihydride Working as a Catalyst in Hydroboration and Dehydrocoupling
Yang Z., Zhong M., Ma X., Nijesh K., De S., Parameswaran P., Roesky H.W.
Journal of the American Chemical Society, 2016
12.
An Aluminum Hydride That Functions like a Transition-Metal Catalyst
Yang Z., Zhong M., Ma X., De S., Anusha C., Parameswaran P., Roesky H.W.
Angewandte Chemie - International Edition, 2015
14.
Aluminum Hydrides Stabilized by N-Heterocyclic Imines as Catalysts for Hydroborations with Pinacolborane
Franz D., Sirtl L., Pöthig A., Inoue S.
Zeitschrift fur Anorganische und Allgemeine Chemie, 2016
15.
Aluminum–Ligand Cooperative N–H Bond Activation and an Example of Dehydrogenative Coupling
Myers T.W., Berben L.A.
Journal of the American Chemical Society, 2013
17.
Catalysis by Aluminum(III) Complexes of Non-Innocent Ligands
Berben L.A.
Chemistry - A European Journal, 2014
18.
Aluminum hydrides with radical-anionic and dianionic acenaphthene-1,2-diimine ligands
Sokolov V.G., Koptseva T.S., Moskalev M.V., Piskunov A.V., Samsonov M.A., Fedushkin I.L.
Russian Chemical Bulletin, 2017
19.
Reactions of Acenaphthenediimine Aluminum Hydride with 1,3-Dicyclohexylcarbodiimide and 2,6-Di-tert-Butyl-4-Methylphenol
Sokolov V.G., Koptseva T.S., Moskalev M.V., Baranov E.V., Fedyushkin I.L.
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2019
20.
Large-scale synthesis of novel sterically hindered acenaphthene-based α-diimine ligands and their application in coordination chemistry
Guo L., Kong W., Xu Y., Yang Y., Ma R., Cong L., Dai S., Liu Z.
Journal of Organometallic Chemistry, 2018
22.
SHELXT– Integrated space-group and crystal-structure determination
Sheldrick G.M.
Acta Crystallographica Section A: Foundations and Advances, 2015
23.
10.1016/j.mencom.2020.01.031_bib0115
Sheldrick
SHELXTL, Version 6.14, 2003
24.
OLEX2: a complete structure solution, refinement and analysis program
Dolomanov O.V., Bourhis L.J., Gildea R.J., Howard J.A., Puschmann H.
Journal of Applied Crystallography, 2009