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Intrinsic infrared absorption for carbon–fluorine bonding in fluorinated nanodiamond

Vladimir Yur'evich Osipov 1, 2
Vladimir Yur'evich Osipov
, 
Nikolai Mikhailovich Romanov 3, 4
Nikolai Mikhailovich Romanov
, 
Kenta Kogane 2
Kenta Kogane
, 
Hidekazu Touhara 5
Hidekazu Touhara
, 
Yoshiyuki Hattori 5
Yoshiyuki Hattori
, 
Kazuyuki Takai 2
Kazuyuki Takai
10.1016/j.mencom.2020.01.028
Published 2019-12-30
Communication , Volume 30, Issue 1, 84-87
19
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Osipov V. Y. et al. Intrinsic infrared absorption for carbon–fluorine bonding in fluorinated nanodiamond // Mendeleev Communications. 2019. Vol. 30. No. 1. pp. 84-87.
GOST all authors (up to 50) Copy
Osipov V. Y., Romanov N. M., Kogane K., Touhara H., Hattori Y., Takai K. Intrinsic infrared absorption for carbon–fluorine bonding in fluorinated nanodiamond // Mendeleev Communications. 2019. Vol. 30. No. 1. pp. 84-87.
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TY - JOUR
DO - 10.1016/j.mencom.2020.01.028
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.01.028
TI - Intrinsic infrared absorption for carbon–fluorine bonding in fluorinated nanodiamond
T2 - Mendeleev Communications
AU - Osipov, Vladimir Yur'evich
AU - Romanov, Nikolai Mikhailovich
AU - Kogane, Kenta
AU - Touhara, Hidekazu
AU - Hattori, Yoshiyuki
AU - Takai, Kazuyuki
PY - 2019
DA - 2019/12/30
PB - Mendeleev Communications
SP - 84-87
IS - 1
VL - 30
ER -
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@article{2019_Osipov,
author = {Vladimir Yur'evich Osipov and Nikolai Mikhailovich Romanov and Kenta Kogane and Hidekazu Touhara and Yoshiyuki Hattori and Kazuyuki Takai},
title = {Intrinsic infrared absorption for carbon–fluorine bonding in fluorinated nanodiamond},
journal = {Mendeleev Communications},
year = {2019},
volume = {30},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.01.028},
number = {1},
pages = {84--87},
doi = {10.1016/j.mencom.2020.01.028}
}
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Osipov, Vladimir Yur'evich, et al. “Intrinsic infrared absorption for carbon–fluorine bonding in fluorinated nanodiamond.” Mendeleev Communications, vol. 30, no. 1, Dec. 2019, pp. 84-87. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.01.028.

Keywords

carbon–fluorine bonding
detonation nanodiamond
fluorination
infrared spectroscopy
surface chemistry

Abstract

IR spectroscopy of fluorinated detonation nanodiamond demonstrates that an intense absorption band at ∼1344 cm–1 and two smaller ones at ∼1324 and ∼1258 cm–1 form the extended low wave-number wing of the observed consolidated spectrum in the range of 1100–1400 cm–1. The intrinsic infrared absorption of CFx bonding at the nanodiamond surface sites has been determined after subtraction of the contribution from remaining C–O and C–O–C groups inside the aggregates of tightly-bonded fundamental nanodiamond particles, which had not been subjected to fluorine attack and to their replacement by fluorine containing groups.

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