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Electrooxidative C–H thiocyanation of hetarenes: voltammetric assessment of thiocyanogen reactivity

Vladimir Alekseevich Kokorekin 1, 2
Vladimir Alekseevich Kokorekin
, 
Ekaterina I Melnikova 1
Ekaterina I Melnikova
, 
Rauza Railevna Yaubasarova 1
Rauza Railevna Yaubasarova
, 
Vladimir Anushavanovich Petrosyan 1
Vladimir Anushavanovich Petrosyan
10.1016/j.mencom.2020.01.023
Published 2019-12-30
Communication , Volume 30, Issue 1, 70-72
8
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Kokorekin V. A. et al. Electrooxidative C–H thiocyanation of hetarenes: voltammetric assessment of thiocyanogen reactivity // Mendeleev Communications. 2019. Vol. 30. No. 1. pp. 70-72.
GOST all authors (up to 50) Copy
Kokorekin V. A., Melnikova E. I., Yaubasarova R. R., Petrosyan V. A. Electrooxidative C–H thiocyanation of hetarenes: voltammetric assessment of thiocyanogen reactivity // Mendeleev Communications. 2019. Vol. 30. No. 1. pp. 70-72.
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TY - JOUR
DO - 10.1016/j.mencom.2020.01.023
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.01.023
TI - Electrooxidative C–H thiocyanation of hetarenes: voltammetric assessment of thiocyanogen reactivity
T2 - Mendeleev Communications
AU - Kokorekin, Vladimir Alekseevich
AU - Melnikova, Ekaterina I
AU - Yaubasarova, Rauza Railevna
AU - Petrosyan, Vladimir Anushavanovich
PY - 2019
DA - 2019/12/30
PB - Mendeleev Communications
SP - 70-72
IS - 1
VL - 30
ER -
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@article{2019_Kokorekin,
author = {Vladimir Alekseevich Kokorekin and Ekaterina I Melnikova and Rauza Railevna Yaubasarova and Vladimir Anushavanovich Petrosyan},
title = {Electrooxidative C–H thiocyanation of hetarenes: voltammetric assessment of thiocyanogen reactivity},
journal = {Mendeleev Communications},
year = {2019},
volume = {30},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.01.023},
number = {1},
pages = {70--72},
doi = {10.1016/j.mencom.2020.01.023}
}
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MLA Copy
Kokorekin, Vladimir Alekseevich, et al. “Electrooxidative C–H thiocyanation of hetarenes: voltammetric assessment of thiocyanogen reactivity.” Mendeleev Communications, vol. 30, no. 1, Dec. 2019, pp. 70-72. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.01.023.

Keywords

aryl thiocyanates
cyclic voltammetry
electrooxidative C–H functionalization
electrosynthesis
hetarenes
nucleophiles

Abstract

The height of thiocyanogen reduction peak on cyclic voltammograms of thiocyanate ion can serve as the criterion for thiocyanogen reactivity towards hetarenes present in the electrolyte. This allows one to predict the efficiency of anodic thiocyanation of various hetarenes.

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