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Floating layer structure of mesogenic phthalocyanine of A3B-type

Alexandr Vasilevich Kazak 1, 2, 3
Alexandr Vasilevich Kazak
, 
Margarita Aleksandrovna Marchenkova 1, 4
Margarita Aleksandrovna Marchenkova
, 
Antonina Igorevna Smirnova 3
Antonina Igorevna Smirnova
, 
Alexey Yur'evich Seregin 1, 4
Alexey Yur'evich Seregin
, 
Alexandr Vladimirovich Rogachev 4, 5
Alexandr Vladimirovich Rogachev
, 
Jonas Warias 6
Jonas Warias
, 
Bridget Murphy 6, 7
Bridget Murphy
, 
Elena Yuryevna Tereshchenko 1, 4
Elena Yuryevna Tereshchenko
, 
Nadezhda Vasil'evna Usol'tseva 3
Nadezhda Vasil'evna Usol'tseva
10.1016/j.mencom.2020.01.017
Published 2019-12-30
Communication , Volume 30, Issue 1, 52-54
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Kazak A. V. et al. Floating layer structure of mesogenic phthalocyanine of A3B-type // Mendeleev Communications. 2019. Vol. 30. No. 1. pp. 52-54.
GOST all authors (up to 50) Copy
Kazak A. V., Marchenkova M. A., Smirnova A. I., Seregin A. Y., Rogachev A. V., Warias J., Murphy B., Tereshchenko E. Y., Usol'tseva N. V. Floating layer structure of mesogenic phthalocyanine of A3B-type // Mendeleev Communications. 2019. Vol. 30. No. 1. pp. 52-54.
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TY - JOUR
DO - 10.1016/j.mencom.2020.01.017
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.01.017
TI - Floating layer structure of mesogenic phthalocyanine of A3B-type
T2 - Mendeleev Communications
AU - Kazak, Alexandr Vasilevich
AU - Marchenkova, Margarita Aleksandrovna
AU - Smirnova, Antonina Igorevna
AU - Seregin, Alexey Yur'evich
AU - Rogachev, Alexandr Vladimirovich
AU - Warias, Jonas
AU - Murphy, Bridget
AU - Tereshchenko, Elena Yuryevna
AU - Usol'tseva, Nadezhda Vasil'evna
PY - 2019
DA - 2019/12/30
PB - Mendeleev Communications
SP - 52-54
IS - 1
VL - 30
ER -
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@article{2019_Kazak,
author = {Alexandr Vasilevich Kazak and Margarita Aleksandrovna Marchenkova and Antonina Igorevna Smirnova and Alexey Yur'evich Seregin and Alexandr Vladimirovich Rogachev and Jonas Warias and Bridget Murphy and Elena Yuryevna Tereshchenko and Nadezhda Vasil'evna Usol'tseva},
title = {Floating layer structure of mesogenic phthalocyanine of A3B-type},
journal = {Mendeleev Communications},
year = {2019},
volume = {30},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.01.017},
number = {1},
pages = {52--54},
doi = {10.1016/j.mencom.2020.01.017}
}
MLA
Cite this
MLA Copy
Kazak, Alexandr Vasilevich, et al. “Floating layer structure of mesogenic phthalocyanine of A3B-type.” Mendeleev Communications, vol. 30, no. 1, Dec. 2019, pp. 52-54. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.01.017.

Keywords

Brewster angle microscopy
floating layers
grazing incidence diffraction
mix-substituted phthalocyanine
structure
X-ray reflectivity

Abstract

To design efficient thin-film materials for low cost organic nanoelectronic devices, the Langmuir floating layer structure of the mesogenic 1,4,8,11,15,18-hexaoctyloxy-22,23,24,25-tetrachlorophthalocyanine (A3B-type) was characterized by Brewster angle microscopy, grazing incidence diffraction, and reflectometry. Starting from the area per one molecule of 7.6nm2, a single two-dimensional ordered structure with the period of 2.3nm was formed. When the area reaches the value of 2.5 nm2, a stable bilayer structure with imperceptible number of 3D aggregates was detected, in which each monolayer preserved organization of the preceding monolayer.

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