Home / Publications / Rearrangement of two 8-membered 1,5-diaza-3,7-diphosphacyclooctane rings into 16-membered P4N4 ligand on the gold(i) template

Rearrangement of two 8-membered 1,5-diaza-3,7-diphosphacyclooctane rings into 16-membered P4N4 ligand on the gold(i) template

Igor Dmitrievich Strelnik 1
Igor Dmitrievich Strelnik
, 
Irina Rishatovna Dayanova 1
Irina Rishatovna Dayanova
, 
Timur M Poryvaev 1
Timur M Poryvaev
, 
Tatiana Pavlovna Gerasimova 1
Tatiana Pavlovna Gerasimova
, 
Igor Anatol'evich Litvinov 1
Igor Anatol'evich Litvinov
, 
Sergey Alexandrovich Katsyuba 1
Sergey Alexandrovich Katsyuba
, 
Èlvira Ilgizovna Musina 1
Èlvira Ilgizovna Musina
, 
Andrey Anatol'evich Karasik 1
Andrey Anatol'evich Karasik
, 
10.1016/j.mencom.2020.01.013
Published 2019-12-30
Communication , Volume 30, Issue 1, 40-42
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Strelnik I. D. et al. Rearrangement of two 8-membered 1,5-diaza-3,7-diphosphacyclooctane rings into 16-membered P4N4 ligand on the gold(i) template // Mendeleev Communications. 2019. Vol. 30. No. 1. pp. 40-42.
GOST all authors (up to 50) Copy
Strelnik I. D., Dayanova I. R., Poryvaev T. M., Gerasimova T. P., Litvinov I. A., Katsyuba S. A., Musina È. I., Karasik A. A., Sinyashin O. G. Rearrangement of two 8-membered 1,5-diaza-3,7-diphosphacyclooctane rings into 16-membered P4N4 ligand on the gold(i) template // Mendeleev Communications. 2019. Vol. 30. No. 1. pp. 40-42.
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TY - JOUR
DO - 10.1016/j.mencom.2020.01.013
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.01.013
TI - Rearrangement of two 8-membered 1,5-diaza-3,7-diphosphacyclooctane rings into 16-membered P4N4 ligand on the gold(i) template
T2 - Mendeleev Communications
AU - Strelnik, Igor Dmitrievich
AU - Dayanova, Irina Rishatovna
AU - Poryvaev, Timur M
AU - Gerasimova, Tatiana Pavlovna
AU - Litvinov, Igor Anatol'evich
AU - Katsyuba, Sergey Alexandrovich
AU - Musina, Èlvira Ilgizovna
AU - Karasik, Andrey Anatol'evich
AU - Sinyashin, Oleg Gerol'dovich
PY - 2019
DA - 2019/12/30
PB - Mendeleev Communications
SP - 40-42
IS - 1
VL - 30
ER -
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@article{2019_Strelnik,
author = {Igor Dmitrievich Strelnik and Irina Rishatovna Dayanova and Timur M Poryvaev and Tatiana Pavlovna Gerasimova and Igor Anatol'evich Litvinov and Sergey Alexandrovich Katsyuba and Èlvira Ilgizovna Musina and Andrey Anatol'evich Karasik and Oleg Gerol'dovich Sinyashin},
title = {Rearrangement of two 8-membered 1,5-diaza-3,7-diphosphacyclooctane rings into 16-membered P4N4 ligand on the gold(i) template},
journal = {Mendeleev Communications},
year = {2019},
volume = {30},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.01.013},
number = {1},
pages = {40--42},
doi = {10.1016/j.mencom.2020.01.013}
}
MLA
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Strelnik, Igor Dmitrievich, et al. “Rearrangement of two 8-membered 1,5-diaza-3,7-diphosphacyclooctane rings into 16-membered P4N4 ligand on the gold(i) template.” Mendeleev Communications, vol. 30, no. 1, Dec. 2019, pp. 40-42. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.01.013.

Keywords

aminomethylphosphines
gold(I) complexes
macrocyclic ligands
tertiary phosphines

Abstract

The reaction of gold(i) chloride with two molecules of 1,5-diaza-3,7-diphosphacyclooctane derivative causes their reorganization into 16-membered macrocyclic tetraphosphine ligand. The structure of the trinuclear gold(i) complex obtained was confirmed by X-ray analysis. The dynamic equilibrium between dinuclear gold(i) complexes with eight-membered cyclic ligands and the trinuclear gold(i) complex with 16-membered ones has been revealed.

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