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Amide derivatives of 3-aminopropylsilatrane

Sergey Nikolaevich Adamovich 1
Sergey Nikolaevich Adamovich
, 
Elizaveta Nikolaevna Oborina 1
Elizaveta Nikolaevna Oborina
, 
Igor Alekseevich Ushakov 2
Igor Alekseevich Ushakov
10.1016/j.mencom.2019.11.029
Published 2019-11-01
Communication , Volume 29, Issue 6, 688-689
5
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Adamovich S. N., Oborina E. N., Ushakov I. A. Amide derivatives of 3-aminopropylsilatrane // Mendeleev Communications. 2019. Vol. 29. No. 6. pp. 688-689.
GOST all authors (up to 50) Copy
Adamovich S. N., Oborina E. N., Ushakov I. A. Amide derivatives of 3-aminopropylsilatrane // Mendeleev Communications. 2019. Vol. 29. No. 6. pp. 688-689.
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TY - JOUR
DO - 10.1016/j.mencom.2019.11.029
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.11.029
TI - Amide derivatives of 3-aminopropylsilatrane
T2 - Mendeleev Communications
AU - Adamovich, Sergey Nikolaevich
AU - Oborina, Elizaveta Nikolaevna
AU - Ushakov, Igor Alekseevich
PY - 2019
DA - 2019/11/01
PB - Mendeleev Communications
SP - 688-689
IS - 6
VL - 29
ER -
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@article{2019_Adamovich,
author = {Sergey Nikolaevich Adamovich and Elizaveta Nikolaevna Oborina and Igor Alekseevich Ushakov},
title = {Amide derivatives of 3-aminopropylsilatrane},
journal = {Mendeleev Communications},
year = {2019},
volume = {29},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.11.029},
number = {6},
pages = {688--689},
doi = {10.1016/j.mencom.2019.11.029}
}
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Adamovich, Sergey Nikolaevich, et al. “Amide derivatives of 3-aminopropylsilatrane.” Mendeleev Communications, vol. 29, no. 6, Nov. 2019, pp. 688-689. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.11.029.

Abstract

Silatranes bearing an amide group in the axial chain have been synthesized by the reaction of 1-(3-aminopropyl)silatrane with arylchalcogenylacetic acids (Het)ArYCH2CO2H [(Het)Ar=2-MeC6H4, 4-Cl-2-MeC6H3, 4-ClC6H4, 3-indolyl; Y=O, S], and their structures have been established by 1H,13C, 15N, 29Si NMR and IR spectroscopy. When 4-chlorophenylsulfonylacetic acid was employed, the reaction proceeded unexpectedly via the 4-chlorophenyl methyl sulfone intermediate and resulted in methyl 4-[3-(1 silatranyl)propylamino]phenyl sulfone.

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