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New heterogeneous catalytic systems based on highly porous ceramic materials modified with immobilized d-metal cage complexes for H2 production from CH4

Alexey Georgievich Dedov 1, 2
Alexey Georgievich Dedov
, 
Yan Zigfridovich Voloshin 1, 2
Yan Zigfridovich Voloshin
, 
Alexander Sergeevich Belov 2
Alexander Sergeevich Belov
, 
Alexey Sergeevich Loktev 1, 2
Alexey Sergeevich Loktev
, 
Alexander Sergeevich Bespalov 3
Alexander Sergeevich Bespalov
, 
Vyacheslav Mikhailovich Buznik 1, 3
Vyacheslav Mikhailovich Buznik
10.1016/j.mencom.2019.11.022
Published 2019-11-01
Communication , Volume 29, Issue 6, 669-671
6
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Dedov A. G. et al. New heterogeneous catalytic systems based on highly porous ceramic materials modified with immobilized d-metal cage complexes for H2 production from CH4 // Mendeleev Communications. 2019. Vol. 29. No. 6. pp. 669-671.
GOST all authors (up to 50) Copy
Dedov A. G., Voloshin Y. Z., Belov A. S., Loktev A. S., Bespalov A. S., Buznik V. M. New heterogeneous catalytic systems based on highly porous ceramic materials modified with immobilized d-metal cage complexes for H2 production from CH4 // Mendeleev Communications. 2019. Vol. 29. No. 6. pp. 669-671.
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TY - JOUR
DO - 10.1016/j.mencom.2019.11.022
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.11.022
TI - New heterogeneous catalytic systems based on highly porous ceramic materials modified with immobilized d-metal cage complexes for H2 production from CH4
T2 - Mendeleev Communications
AU - Dedov, Alexey Georgievich
AU - Voloshin, Yan Zigfridovich
AU - Belov, Alexander Sergeevich
AU - Loktev, Alexey Sergeevich
AU - Bespalov, Alexander Sergeevich
AU - Buznik, Vyacheslav Mikhailovich
PY - 2019
DA - 2019/11/01
PB - Mendeleev Communications
SP - 669-671
IS - 6
VL - 29
ER -
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@article{2019_Dedov,
author = {Alexey Georgievich Dedov and Yan Zigfridovich Voloshin and Alexander Sergeevich Belov and Alexey Sergeevich Loktev and Alexander Sergeevich Bespalov and Vyacheslav Mikhailovich Buznik},
title = {New heterogeneous catalytic systems based on highly porous ceramic materials modified with immobilized d-metal cage complexes for H2 production from CH4},
journal = {Mendeleev Communications},
year = {2019},
volume = {29},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.11.022},
number = {6},
pages = {669--671},
doi = {10.1016/j.mencom.2019.11.022}
}
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Dedov, Alexey Georgievich, et al. “New heterogeneous catalytic systems based on highly porous ceramic materials modified with immobilized d-metal cage complexes for H2 production from CH4.” Mendeleev Communications, vol. 29, no. 6, Nov. 2019, pp. 669-671. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.11.022.

Abstract

The Fe, Co and Ru clathrochelates bearing terminal polar groups were immobilized as the precursors of single atom catalysts on a surface of highly porous ceramic material used as the support. The obtained materials, which were evaluated for a syngas production from CH4 based on its partial oxidation and dry reforming reactions, did not catalyze the partial oxidation of CH4, while that based on immobilized RuII clathrochelate served as the active and selective catalyst of dry reforming conversion of CH4+CO2 mixture into a syngas containing the equimolar amounts of H2 and CO.

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