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Syntheses of chiral fused 4,5-diazafluorene–bis(nopinane) derivatives

Eugene Sergeevich Vasilyev 1
Eugene Sergeevich Vasilyev
, 
Sergey Nikolaevich Bizyaev 1
Sergey Nikolaevich Bizyaev
, 
Vladislav Yur'evich Komarov 2, 3
Vladislav Yur'evich Komarov
, 
Alexey Vasil'evich Tkachev 1, 2
Alexey Vasil'evich Tkachev
10.1016/j.mencom.2019.09.036
Published 2019-09-04
Communication , Volume 29, Issue 5, 584-586
3
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Vasilyev E. S. et al. Syntheses of chiral fused 4,5-diazafluorene–bis(nopinane) derivatives // Mendeleev Communications. 2019. Vol. 29. No. 5. pp. 584-586.
GOST all authors (up to 50) Copy
Vasilyev E. S., Bizyaev S. N., Komarov V. Y., Tkachev A. V. Syntheses of chiral fused 4,5-diazafluorene–bis(nopinane) derivatives // Mendeleev Communications. 2019. Vol. 29. No. 5. pp. 584-586.
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TY - JOUR
DO - 10.1016/j.mencom.2019.09.036
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.09.036
TI - Syntheses of chiral fused 4,5-diazafluorene–bis(nopinane) derivatives
T2 - Mendeleev Communications
AU - Vasilyev, Eugene Sergeevich
AU - Bizyaev, Sergey Nikolaevich
AU - Komarov, Vladislav Yur'evich
AU - Tkachev, Alexey Vasil'evich
PY - 2019
DA - 2019/09/04
PB - Mendeleev Communications
SP - 584-586
IS - 5
VL - 29
ER -
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@article{2019_Vasilyev,
author = {Eugene Sergeevich Vasilyev and Sergey Nikolaevich Bizyaev and Vladislav Yur'evich Komarov and Alexey Vasil'evich Tkachev},
title = {Syntheses of chiral fused 4,5-diazafluorene–bis(nopinane) derivatives},
journal = {Mendeleev Communications},
year = {2019},
volume = {29},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.09.036},
number = {5},
pages = {584--586},
doi = {10.1016/j.mencom.2019.09.036}
}
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Vasilyev, Eugene Sergeevich, et al. “Syntheses of chiral fused 4,5-diazafluorene–bis(nopinane) derivatives.” Mendeleev Communications, vol. 29, no. 5, Sep. 2019, pp. 584-586. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.09.036.

Abstract

Reaction of fused 4,5-diazafluorene–bis(nopinane) with tere-phthalaldehyde, benzophenone, ninhydrin or anthraquinone in THF in the presence of TiCl4 and pyridine results in a formation of new chiral condensation products, which exhibit solvatochromism and pleochroism. Crystal structure of the key products has been determined by X-ray crystallography, and unusual colour behavior has been explained by DFT calculations.

References

6.
Allosteric Regulation of the Rotational Speed in a Light-Driven Molecular Motor
Faulkner A., van Leeuwen T., Feringa B.L., Wezenberg S.J.
Journal of the American Chemical Society, 2016
9.
Synthesis and properties of novel crown ether-annelated 4′,5′-diaza-9′-(1,3-dithiole-2-ylidene)-fluorenes and their ruthenium(II) complexes
Sako K., Kakehi T., Nakano S., Oku H., Shen X.F., Iwanaga T., Yoshikawa M., Sugahara K., Toyota S., Takemura H., Shinmyozu T., Shiotsuka M., Tatemitsu H.
Tetrahedron Letters, 2014
10.
Synthesis and redox properties of π-conjugated 4,5-diazafluorene derivatives incorporating 9-cyanomethylene moiety as an electron acceptor
Sako K., Mugishima Y., Iwanaga T., Toyota S., Takemura H., Watanabe M., Shinmyozu T., Shiotsuka M., Tatemitsu H.
Tetrahedron Letters, 2011
13.
Self-assembly of Ag(I) helicates with new enantiopure 5,6-Chiragen type ligands
Mamula O., Bark T., Quinodoz B., Stoeckli-Evans H., von Zelewsky A.
Inorganica Chimica Acta, 2018
14.
Versatile synthesis of chiral 6-oxoverdazyl radical ligands – new building blocks for multifunctional molecule-based magnets
Solea A.B., Wohlhauser T., Abbasi P., Mongbanziama Y., Crochet A., Fromm K.M., Novitchi G., Train C., Pilkington M., Mamula O.
Dalton Transactions, 2018
15.
A short history of SHELX
Sheldrick G.M.
Acta Crystallographica Section A Foundations of Crystallography, 2007
16.
OLEX2: a complete structure solution, refinement and analysis program
Dolomanov O.V., Bourhis L.J., Gildea R.J., Howard J.A., Puschmann H.
Journal of Applied Crystallography, 2009
19.
10.1016/j.mencom.2019.09.036_bib0095
Neese
Wiley Interdisp. Rev.: Comput. Mol. Sci., 2012