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α-Diphenylphosphino-N-(pyrazin-2-yl)glycine as a ligand in Ni-catalyzed ethylene oligomerization

Olga S Soficheva 1
Olga S Soficheva
, 
Giyjaz Èduardovich Bekmukhamedov 1, 2
Giyjaz Èduardovich Bekmukhamedov
, 
Alexey Borisovich Dobrynin 1
Alexey Borisovich Dobrynin
, 
Joachim W Heinicke 3
Joachim W Heinicke
,  , 
Dmitry Grigorievich Yakhvarov 1, 2
Dmitry Grigorievich Yakhvarov
10.1016/j.mencom.2019.09.033
Published 2019-09-04
Communication , Volume 29, Issue 5, 575-577
12
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Soficheva O. S. et al. α-Diphenylphosphino-N-(pyrazin-2-yl)glycine as a ligand in Ni-catalyzed ethylene oligomerization // Mendeleev Communications. 2019. Vol. 29. No. 5. pp. 575-577.
GOST all authors (up to 50) Copy
Soficheva O. S., Bekmukhamedov G. È., Dobrynin A. B., Heinicke J. W., Sinyashin O. G., Yakhvarov D. G. α-Diphenylphosphino-N-(pyrazin-2-yl)glycine as a ligand in Ni-catalyzed ethylene oligomerization // Mendeleev Communications. 2019. Vol. 29. No. 5. pp. 575-577.
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TY - JOUR
DO - 10.1016/j.mencom.2019.09.033
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.09.033
TI - α-Diphenylphosphino-N-(pyrazin-2-yl)glycine as a ligand in Ni-catalyzed ethylene oligomerization
T2 - Mendeleev Communications
AU - Soficheva, Olga S
AU - Bekmukhamedov, Giyjaz Èduardovich
AU - Dobrynin, Alexey Borisovich
AU - Heinicke, Joachim W
AU - Sinyashin, Oleg Gerol'dovich
AU - Yakhvarov, Dmitry Grigorievich
PY - 2019
DA - 2019/09/04
PB - Mendeleev Communications
SP - 575-577
IS - 5
VL - 29
ER -
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@article{2019_Soficheva,
author = {Olga S Soficheva and Giyjaz Èduardovich Bekmukhamedov and Alexey Borisovich Dobrynin and Joachim W Heinicke and Oleg Gerol'dovich Sinyashin and Dmitry Grigorievich Yakhvarov},
title = {α-Diphenylphosphino-N-(pyrazin-2-yl)glycine as a ligand in Ni-catalyzed ethylene oligomerization},
journal = {Mendeleev Communications},
year = {2019},
volume = {29},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.09.033},
number = {5},
pages = {575--577},
doi = {10.1016/j.mencom.2019.09.033}
}
MLA
Cite this
MLA Copy
Soficheva, Olga S., et al. “α-Diphenylphosphino-N-(pyrazin-2-yl)glycine as a ligand in Ni-catalyzed ethylene oligomerization.” Mendeleev Communications, vol. 29, no. 5, Sep. 2019, pp. 575-577. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.09.033.

Abstract

α-Diphenylphosphino-N-(pyrazin-2-yl)glycine was synthesized by the three-component condensation of diphenylphosphine, glyoxylic acid hydrate, and 2-aminopyrazine and its structure was confirmed by X-ray diffraction. It reacted with [Ni(COD)2] (COD is cycloocta-1,5-diene) to give complexes that were tested as catalysts for selective dimerization/oligomerization of ethylene to but-1-ene (main product) and C6–C14 α-olefins, respectively.

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