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New bis-rhodium complex with a bidentate 3-phosphino-1,2,3,6-tetrahydrophosphinine P-ligand

Irina Leonovna Odinets 1
Irina Leonovna Odinets
, 
Tamás Körtvélyesi 2
Tamás Körtvélyesi
, 
Réka Herbay 3
Réka Herbay
, 
Péter Bagi 3
Péter Bagi
, 
10.1016/j.mencom.2019.09.032
Published 2019-09-04
Communication , Volume 29, Issue 5, 573-574
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Odinets I. L. et al. New bis-rhodium complex with a bidentate 3-phosphino-1,2,3,6-tetrahydrophosphinine P-ligand // Mendeleev Communications. 2019. Vol. 29. No. 5. pp. 573-574.
GOST all authors (up to 50) Copy
Odinets I. L., Körtvélyesi T., Herbay R., Bagi P., Keglevich G. T. New bis-rhodium complex with a bidentate 3-phosphino-1,2,3,6-tetrahydrophosphinine P-ligand // Mendeleev Communications. 2019. Vol. 29. No. 5. pp. 573-574.
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TY - JOUR
DO - 10.1016/j.mencom.2019.09.032
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.09.032
TI - New bis-rhodium complex with a bidentate 3-phosphino-1,2,3,6-tetrahydrophosphinine P-ligand
T2 - Mendeleev Communications
AU - Odinets, Irina Leonovna
AU - Körtvélyesi, Tamás
AU - Herbay, Réka
AU - Bagi, Péter
AU - Keglevich, György Tibor
PY - 2019
DA - 2019/09/04
PB - Mendeleev Communications
SP - 573-574
IS - 5
VL - 29
ER -
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@article{2019_Odinets,
author = {Irina Leonovna Odinets and Tamás Körtvélyesi and Réka Herbay and Péter Bagi and György Tibor Keglevich},
title = {New bis-rhodium complex with a bidentate 3-phosphino-1,2,3,6-tetrahydrophosphinine P-ligand},
journal = {Mendeleev Communications},
year = {2019},
volume = {29},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.09.032},
number = {5},
pages = {573--574},
doi = {10.1016/j.mencom.2019.09.032}
}
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Odinets, Irina Leonovna, et al. “New bis-rhodium complex with a bidentate 3-phosphino-1,2,3,6-tetrahydrophosphinine P-ligand.” Mendeleev Communications, vol. 29, no. 5, Sep. 2019, pp. 573-574. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.09.032.

Abstract

Reaction between the title bidental P-ligand (obtained from 4-chloro-5-methyl-1-phenyl-3-diphenylphosphoryl-l,2,3,6-tetrahydrophosphinine oxide by double deoxygenation using trichlorosilane or phenylsilane) and two equivalents of (Me5C5)RhCl2 led to the corresponding bis-RhIII complex whose structure was evaluated by ab initio and DFT calculations. Attempts to achieve selective complexation of either the ring or exocyclic P-function were unsuccessful.

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