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Copper(I) complex with BINAP and 3,5-dimethylpyrazole: synthesis and photoluminescent properties

,  , 
Alexander Fedorovich Smol'yakov 1, 2, 3
Alexander Fedorovich Smol'yakov
, 
Alexey Alexandrovich Averin 4
Alexey Alexandrovich Averin
, 
10.1016/j.mencom.2019.09.031
Published 2019-09-04
Communication , Volume 29, Issue 5, 570-572
11
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Titov A. A. et al. Copper(I) complex with BINAP and 3,5-dimethylpyrazole: synthesis and photoluminescent properties // Mendeleev Communications. 2019. Vol. 29. No. 5. pp. 570-572.
GOST all authors (up to 50) Copy
Titov A. A., Filippov O. A., Smol'yakov A. F., Averin A. A., Shubina E. S. Copper(I) complex with BINAP and 3,5-dimethylpyrazole: synthesis and photoluminescent properties // Mendeleev Communications. 2019. Vol. 29. No. 5. pp. 570-572.
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TY - JOUR
DO - 10.1016/j.mencom.2019.09.031
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.09.031
TI - Copper(I) complex with BINAP and 3,5-dimethylpyrazole: synthesis and photoluminescent properties
T2 - Mendeleev Communications
AU - Titov, Aleksei Aleksandrovich
AU - Filippov, Oleg Andreevich
AU - Smol'yakov, Alexander Fedorovich
AU - Averin, Alexey Alexandrovich
AU - Shubina, Elena Solomonovna
PY - 2019
DA - 2019/09/04
PB - Mendeleev Communications
SP - 570-572
IS - 5
VL - 29
ER -
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@article{2019_Titov,
author = {Aleksei Aleksandrovich Titov and Oleg Andreevich Filippov and Alexander Fedorovich Smol'yakov and Alexey Alexandrovich Averin and Elena Solomonovna Shubina},
title = {Copper(I) complex with BINAP and 3,5-dimethylpyrazole: synthesis and photoluminescent properties},
journal = {Mendeleev Communications},
year = {2019},
volume = {29},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.09.031},
number = {5},
pages = {570--572},
doi = {10.1016/j.mencom.2019.09.031}
}
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Titov, Aleksei Aleksandrovich, et al. “Copper(I) complex with BINAP and 3,5-dimethylpyrazole: synthesis and photoluminescent properties.” Mendeleev Communications, vol. 29, no. 5, Sep. 2019, pp. 570-572. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.09.031.

Abstract

A reaction of [Cu(MeCN)4]BF4 with PzH (3,5-dimethylpyrazole) and BINAP [2,20-bis(diphenylphosphino)-1,10-binaphthyl] leads to the formation of mononuclear CuI complex [Cu(PzH)(BINAP)]BF4 containing the molecule of nondeprotonated pyrazole and one BINAP ligand with two phosphorus atoms chelating the metal. This complex exhibits a bright phosphorescence originating from the 3(M+L)LCT state at room temperature. At 77K, the emission is splitted into two components: 3(M+L)LCT and 3LC transitions.

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