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Catalytic system based on nickel(II) acetate and hypophosphorous acid for the selective hydrodeoxygenation of guaiacol

Maria Andreevna Golubeva 1
Maria Andreevna Golubeva
, 
Anton L'vovich Maksimov 1, 2
Anton L'vovich Maksimov
10.1016/j.mencom.2019.09.024
Published 2019-09-04
Communication , Volume 29, Issue 5, 550-552
9
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Golubeva M. A., Maksimov A. L. Catalytic system based on nickel(II) acetate and hypophosphorous acid for the selective hydrodeoxygenation of guaiacol // Mendeleev Communications. 2019. Vol. 29. No. 5. pp. 550-552.
GOST all authors (up to 50) Copy
Golubeva M. A., Maksimov A. L. Catalytic system based on nickel(II) acetate and hypophosphorous acid for the selective hydrodeoxygenation of guaiacol // Mendeleev Communications. 2019. Vol. 29. No. 5. pp. 550-552.
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TY - JOUR
DO - 10.1016/j.mencom.2019.09.024
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.09.024
TI - Catalytic system based on nickel(II) acetate and hypophosphorous acid for the selective hydrodeoxygenation of guaiacol
T2 - Mendeleev Communications
AU - Golubeva, Maria Andreevna
AU - Maksimov, Anton L'vovich
PY - 2019
DA - 2019/09/04
PB - Mendeleev Communications
SP - 550-552
IS - 5
VL - 29
ER -
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@article{2019_Golubeva,
author = {Maria Andreevna Golubeva and Anton L'vovich Maksimov},
title = {Catalytic system based on nickel(II) acetate and hypophosphorous acid for the selective hydrodeoxygenation of guaiacol},
journal = {Mendeleev Communications},
year = {2019},
volume = {29},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.09.024},
number = {5},
pages = {550--552},
doi = {10.1016/j.mencom.2019.09.024}
}
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Golubeva, Maria Andreevna, and Anton L'vovich Maksimov. “Catalytic system based on nickel(II) acetate and hypophosphorous acid for the selective hydrodeoxygenation of guaiacol.” Mendeleev Communications, vol. 29, no. 5, Sep. 2019, pp. 550-552. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.09.024.

Abstract

The title catalytic system exhibited high activity in the hydrogenation–hydrodeoxygenation of guaiacol (a low-molecular-weight product of lignin degradation). The conversion of guaiacol reached 97%, and the selectivity for cyclohexane was as high as 94%. Nickel phosphide phases were obtained in the reaction medium, and their presence determined the high activity of the catalytic system in the hydroconversion of guaiacol.

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