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N,S-containing soft ligands for extractive separation of f-metals: synthesis and unexpected inverse selectivity

Gladis Gidovna Zakirova 1
Gladis Gidovna Zakirova
,  , 
Dmitriy Yur'evich Mladentsev 1
Dmitriy Yur'evich Mladentsev
, 
Maria Valer'evna Evsiunina 1
Maria Valer'evna Evsiunina
, 
Victor Aleksandrovich Tafeenko 1
Victor Aleksandrovich Tafeenko
, 
Natalia Evgen'evna Borisova 1
Natalia Evgen'evna Borisova
10.1016/j.mencom.2019.07.037
Published 2019-07-01
Communication , Volume 29, Issue 4, 463-465
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Zakirova G. G. et al. N,S-containing soft ligands for extractive separation of f-metals: synthesis and unexpected inverse selectivity // Mendeleev Communications. 2019. Vol. 29. No. 4. pp. 463-465.
GOST all authors (up to 50) Copy
Zakirova G. G., Matveev P. I., Mladentsev D. Y., Evsiunina M. V., Tafeenko V. A., Borisova N. E. N,S-containing soft ligands for extractive separation of f-metals: synthesis and unexpected inverse selectivity // Mendeleev Communications. 2019. Vol. 29. No. 4. pp. 463-465.
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TY - JOUR
DO - 10.1016/j.mencom.2019.07.037
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.07.037
TI - N,S-containing soft ligands for extractive separation of f-metals: synthesis and unexpected inverse selectivity
T2 - Mendeleev Communications
AU - Zakirova, Gladis Gidovna
AU - Matveev, Petr Igorevich
AU - Mladentsev, Dmitriy Yur'evich
AU - Evsiunina, Maria Valer'evna
AU - Tafeenko, Victor Aleksandrovich
AU - Borisova, Natalia Evgen'evna
PY - 2019
DA - 2019/07/01
PB - Mendeleev Communications
SP - 463-465
IS - 4
VL - 29
ER -
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@article{2019_Zakirova,
author = {Gladis Gidovna Zakirova and Petr Igorevich Matveev and Dmitriy Yur'evich Mladentsev and Maria Valer'evna Evsiunina and Victor Aleksandrovich Tafeenko and Natalia Evgen'evna Borisova},
title = {N,S-containing soft ligands for extractive separation of f-metals: synthesis and unexpected inverse selectivity},
journal = {Mendeleev Communications},
year = {2019},
volume = {29},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.07.037},
number = {4},
pages = {463--465},
doi = {10.1016/j.mencom.2019.07.037}
}
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Zakirova, Gladis Gidovna, et al. “N,S-containing soft ligands for extractive separation of f-metals: synthesis and unexpected inverse selectivity.” Mendeleev Communications, vol. 29, no. 4, Jul. 2019, pp. 463-465. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.07.037.

Abstract

A number of heterocycle-based bis(phosphine sulfides) have been synthesized from the corresponding phosphine oxides using phosphorus(v) sulfide in good to excellent yields, for one representative compound the molecular structure has been determined by single crystal X-ray diffraction. The compounds obtained were tested as extractants for f-metals both in nitric acid and ammonium nitrate media, distribution coefficients and selectivity factors have been determined for an Am/Eu pair.

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