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Noncovalent bonding of copper atoms to the nitrogen-containing sites of hydrogenated diamond surfaces

Vladimir Yur'evich Osipov 1, 2
Vladimir Yur'evich Osipov
, 
Danil Wladimirovich Boukhvalov 3, 4
Danil Wladimirovich Boukhvalov
, 
Kazuyuki Takai 2
Kazuyuki Takai
10.1016/j.mencom.2019.07.033
Published 2019-07-01
Communication , Volume 29, Issue 4, 452-454
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Osipov V. Y., Boukhvalov D. W., Takai K. Noncovalent bonding of copper atoms to the nitrogen-containing sites of hydrogenated diamond surfaces // Mendeleev Communications. 2019. Vol. 29. No. 4. pp. 452-454.
GOST all authors (up to 50) Copy
Osipov V. Y., Boukhvalov D. W., Takai K. Noncovalent bonding of copper atoms to the nitrogen-containing sites of hydrogenated diamond surfaces // Mendeleev Communications. 2019. Vol. 29. No. 4. pp. 452-454.
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TY - JOUR
DO - 10.1016/j.mencom.2019.07.033
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.07.033
TI - Noncovalent bonding of copper atoms to the nitrogen-containing sites of hydrogenated diamond surfaces
T2 - Mendeleev Communications
AU - Osipov, Vladimir Yur'evich
AU - Boukhvalov, Danil Wladimirovich
AU - Takai, Kazuyuki
PY - 2019
DA - 2019/07/01
PB - Mendeleev Communications
SP - 452-454
IS - 4
VL - 29
ER -
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@article{2019_Osipov,
author = {Vladimir Yur'evich Osipov and Danil Wladimirovich Boukhvalov and Kazuyuki Takai},
title = {Noncovalent bonding of copper atoms to the nitrogen-containing sites of hydrogenated diamond surfaces},
journal = {Mendeleev Communications},
year = {2019},
volume = {29},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.07.033},
number = {4},
pages = {452--454},
doi = {10.1016/j.mencom.2019.07.033}
}
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Osipov, Vladimir Yur'evich, et al. “Noncovalent bonding of copper atoms to the nitrogen-containing sites of hydrogenated diamond surfaces.” Mendeleev Communications, vol. 29, no. 4, Jul. 2019, pp. 452-454. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.07.033.

Abstract

We demonstrate that isolated copper atoms can be bound to the four-coordinated surface nitrogen sites of a diamond lattice fully terminated by atomic hydrogen. This bonding is related to the ability of surface nitrogen sites to donate unpaired electrons (from an antibonding orbital) to third alien surface agents.

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