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Solvation and ion–ion interactions in aqueous and non-aqueous solutions of cationic cytostatic agent prospidium chloride

Andrey Vladimirovich Kustov 1, 2
Andrey Vladimirovich Kustov
, 
Tatyana Vladimirovna Kudayarova 2
Tatyana Vladimirovna Kudayarova
, 
Olga A Antonova 1, 2
Olga A Antonova
, 
Nataliya Leonidovna Smirnova 1, 2
Nataliya Leonidovna Smirnova
, 
Andrey Atikovich Kladiev 3
Andrey Atikovich Kladiev
, 
Arseniy Andreevich Kladiev 4
Arseniy Andreevich Kladiev
10.1016/j.mencom.2019.07.029
Published 2019-07-01
Communication , Volume 29, Issue 4, 441-443
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Kustov A. V. et al. Solvation and ion–ion interactions in aqueous and non-aqueous solutions of cationic cytostatic agent prospidium chloride // Mendeleev Communications. 2019. Vol. 29. No. 4. pp. 441-443.
GOST all authors (up to 50) Copy
Kustov A. V., Kudayarova T. V., Antonova O. A., Smirnova N. L., Kladiev A. A., Kladiev A. A. Solvation and ion–ion interactions in aqueous and non-aqueous solutions of cationic cytostatic agent prospidium chloride // Mendeleev Communications. 2019. Vol. 29. No. 4. pp. 441-443.
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TY - JOUR
DO - 10.1016/j.mencom.2019.07.029
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.07.029
TI - Solvation and ion–ion interactions in aqueous and non-aqueous solutions of cationic cytostatic agent prospidium chloride
T2 - Mendeleev Communications
AU - Kustov, Andrey Vladimirovich
AU - Kudayarova, Tatyana Vladimirovna
AU - Antonova, Olga A
AU - Smirnova, Nataliya Leonidovna
AU - Kladiev, Andrey Atikovich
AU - Kladiev, Arseniy Andreevich
PY - 2019
DA - 2019/07/01
PB - Mendeleev Communications
SP - 441-443
IS - 4
VL - 29
ER -
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@article{2019_Kustov,
author = {Andrey Vladimirovich Kustov and Tatyana Vladimirovna Kudayarova and Olga A Antonova and Nataliya Leonidovna Smirnova and Andrey Atikovich Kladiev and Arseniy Andreevich Kladiev},
title = {Solvation and ion–ion interactions in aqueous and non-aqueous solutions of cationic cytostatic agent prospidium chloride},
journal = {Mendeleev Communications},
year = {2019},
volume = {29},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.07.029},
number = {4},
pages = {441--443},
doi = {10.1016/j.mencom.2019.07.029}
}
MLA
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Kustov, Andrey Vladimirovich, et al. “Solvation and ion–ion interactions in aqueous and non-aqueous solutions of cationic cytostatic agent prospidium chloride.” Mendeleev Communications, vol. 29, no. 4, Jul. 2019, pp. 441-443. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.07.029.

Abstract

The thermochemical behavior of well-established heterocyclic anticancer drug, prospidium chloride, was comparatively evaluated in water and two other non-aqueous solvents, formamide and ethylene glycol, forming the three dimensional H-bond network. Standard enthalpies and heat capacities of solution, as well as, enthalpic parameters of solute–solute pair interactions were estimated at 298 and 318K and compared with the available values for some ionic species. A linear correlation between the energetics of ion–ion interactions and the reciprocal dielectric constant of the medium for tetraethylammonium bromide and prospidium chloride was revealed.

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