Home / Publications / Condensation of all-cis-tetraphenylcyclotetrasiloxanetetraol in ammonia: new method for preparation of ladder-like polyphenylsilsesquioxanes

Condensation of all-cis-tetraphenylcyclotetrasiloxanetetraol in ammonia: new method for preparation of ladder-like polyphenylsilsesquioxanes

Anton Aleksandrovich Anisimov 1
Anton Aleksandrovich Anisimov
, 
Nataliya Vladimirovna Polshchikova 1
Nataliya Vladimirovna Polshchikova
, 
Yuliya Stanislavovna Vysochinskaya 1, 2
Yuliya Stanislavovna Vysochinskaya
, 
Pavel Aleksandrovich Zader 3
Pavel Aleksandrovich Zader
,  , 
Aleksandr Sergeevich Peregudov 1
Aleksandr Sergeevich Peregudov
,  , 
Olga Ivanovna Shchegolikhina 1
Olga Ivanovna Shchegolikhina
, 
Aziz Mansurovich Muzafarov 1, 2
Aziz Mansurovich Muzafarov
10.1016/j.mencom.2019.07.022
Published 2019-07-01
Communication , Volume 29, Issue 4, 421-423
24
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Anisimov A. A. et al. Condensation of all-cis-tetraphenylcyclotetrasiloxanetetraol in ammonia: new method for preparation of ladder-like polyphenylsilsesquioxanes // Mendeleev Communications. 2019. Vol. 29. No. 4. pp. 421-423.
GOST all authors (up to 50) Copy
Anisimov A. A., Polshchikova N. V., Vysochinskaya Y. S., Zader P. A., Nikiforova G. G., Peregudov A. S., Buzin M. I., Shchegolikhina O. I., Muzafarov A. M. Condensation of all-cis-tetraphenylcyclotetrasiloxanetetraol in ammonia: new method for preparation of ladder-like polyphenylsilsesquioxanes // Mendeleev Communications. 2019. Vol. 29. No. 4. pp. 421-423.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2019.07.022
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.07.022
TI - Condensation of all-cis-tetraphenylcyclotetrasiloxanetetraol in ammonia: new method for preparation of ladder-like polyphenylsilsesquioxanes
T2 - Mendeleev Communications
AU - Anisimov, Anton Aleksandrovich
AU - Polshchikova, Nataliya Vladimirovna
AU - Vysochinskaya, Yuliya Stanislavovna
AU - Zader, Pavel Aleksandrovich
AU - Nikiforova, Galina Grigoryevna
AU - Peregudov, Aleksandr Sergeevich
AU - Buzin, Mikhail Igorevich
AU - Shchegolikhina, Olga Ivanovna
AU - Muzafarov, Aziz Mansurovich
PY - 2019
DA - 2019/07/01
PB - Mendeleev Communications
SP - 421-423
IS - 4
VL - 29
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2019_Anisimov,
author = {Anton Aleksandrovich Anisimov and Nataliya Vladimirovna Polshchikova and Yuliya Stanislavovna Vysochinskaya and Pavel Aleksandrovich Zader and Galina Grigoryevna Nikiforova and Aleksandr Sergeevich Peregudov and Mikhail Igorevich Buzin and Olga Ivanovna Shchegolikhina and Aziz Mansurovich Muzafarov},
title = {Condensation of all-cis-tetraphenylcyclotetrasiloxanetetraol in ammonia: new method for preparation of ladder-like polyphenylsilsesquioxanes},
journal = {Mendeleev Communications},
year = {2019},
volume = {29},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.07.022},
number = {4},
pages = {421--423},
doi = {10.1016/j.mencom.2019.07.022}
}
MLA
Cite this
MLA Copy
Anisimov, Anton Aleksandrovich, et al. “Condensation of all-cis-tetraphenylcyclotetrasiloxanetetraol in ammonia: new method for preparation of ladder-like polyphenylsilsesquioxanes.” Mendeleev Communications, vol. 29, no. 4, Jul. 2019, pp. 421-423. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.07.022.

Abstract

One-step method for the preparation of polyphenylsilsesqui oxane by condensation of all-cis-1,3,5,7-tetraphenyl-1,3,5,7 tetrahydroxycyclotetrasiloxane in liquid ammonia has been developed. This method makes it possible to produce high molecular weight polymers with regular structure in the absence of organic solvent. The structure of the polymer product was confirmed by 1H and 29Si NMR spectroscopy, GPC, IR spectroscopy, powder X-ray diffraction and viscosimetry.

References

1.
Silsesquioxanes
Baney R.H., Itoh M., Sakakibara A., Suzuki T.
Chemical Reviews, 1995
3.
Promising Functional Materials Based on Ladder Polysiloxanes
Zhou Q., Yan S., Han C.C., Xie P., Zhang R.
Advanced Materials, 2008
4.
Lee H.S., Choi S., Baek K., Lee E.C., Hong S.M., Lee J., Hwang S.S.
Macromolecular Research, 2012
5.
DOUBLE CHAIN POLYMERS OF PHENYLSILSESQUIOXANE
Brown J.F., Vogt L.H., Katchman A., Eustance J.W., Kiser K.M., Krantz K.W.
Journal of the American Chemical Society, 1960
6.
Synthesis and physico-chemical properties of polyphenyl silsesquioxanes
Andrianov K.A., Pavlova S.A., Tverdokhlebova I.I., Yemel'yanov V.N., Larina T.A., Rabkina A.Y.
Polymer Science U S S R, 1972
7.
On the polycondensation products of cis-(1,3,5,7-tetrahydroxy)-1,3,5,7-tetraphenylcyclo-tetrasiloxane
Andrianov K.A., Tverdokhlebova I.I., Makarova N.N., Mamayeva I.I., Chekalov A.K., Men'shov V.M., Pavlova S.-.
Polymer Science U S S R, 1978
8.
One-Step Synthesis of Thermoplastic Phenylsilsesquioxane Polymer and Its Copolymers with Diphenylsiloxanes
Leśniak E., Michalska Z.M., Chojnowski J.
Journal of Inorganic and Organometallic Polymers, 1998
9.
Surfactant and pH-Mediated Control over the Molecular Structure of Poly(phenylsilsesquioxane) Resins
Harreld J.H., Su K., Katsoulis D.E., Suto M., Stucky G.D.
Chemistry of Materials, 2002
10.
Synthesis of ladder-like polyphenylsilsesquioxanes with fairly high regularity using 1,2-ethylenediamine as endo-template
Yang X., Cao C., Chen Z., Liu J., Luo M., Lai G.
Chinese Journal of Polymer Science (English Edition), 2015
11.
Oligo- and polysiloxanes
Abe Y., Gunji T.
Progress in Polymer Science, 2004
12.
Mechanism for the Formation of Poly(phenylsilsesquioxane)
Yamamoto S., Yasuda N., Ueyama A., Adachi H., Ishikawa M.
Macromolecules, 2004
14.
Synthesis of ladder polyphenylsilsesquioxane with columnar structure
Petrova I.M., Buryak A.K., Dolgushin F.M., Peregudov A.S., Klemenkova Z.S., Makarova N.N.
Russian Chemical Bulletin, 2014
16.
A Study of the Polycondensation of (Tetrahydroxy)(Tetraaryl)Cyclotetrasiloxanes under Equilibrium and Non-Equilibrium Conditions in the Presence and Absence of Montmorillonite
Makarova N., Lyakhovetsky Y., Petrova I., Dolgushin F., Ikonnikov N., Peregudov A., Strelkova T., Klemenkova Z.
Polymers, 2018
19.
Synthesis and conformational characteristics of some ladder polyphenylsiloxanes
Andrianov K.A., Bushin S.V., Vitovskaya M.G., Yemel'yanov V.N., Lavrenko P.N., Makarova N.N., Muzafarov A.M., Nikolayev V.Y., Kolbina G.F., Shtennikova I.N., Tsvetkov V.N.
Polymer Science U S S R, 1977
20.
10.1016/j.mencom.2019.07.022_bib0070
Walkowiak
2018
21.
The Polycondensation of Phenylsilanetriol
Brown J.F.
Journal of the American Chemical Society, 1965
22.
Synthesis and Properties of Stereoregular Cyclic Polysilanols:  cis-[PhSi(O)OH]4, cis-[PhSi(O)OH]6, and Tris-cis-tris-trans-[PhSi(O)OH]12
Shchegolikhina O.I., Pozdnyakova Y.A., Molodtsova Y.A., Korkin S.D., Bukalov S.S., Leites L.A., Lyssenko K.A., Peregudov A.S., Auner N., Katsoulis D.E.
Inorganic Chemistry, 2002
23.
Vysochinskaya Y.S., Anisimov A.A., Milenin S.A., Korlyukov A.A., Dolgushin F.M., Kononova E.G., Peregudov A.S., Buzin M.I., Shchegolikhina O.I., Muzafarov A.M.
Mendeleev Communications, 2018
25.
Molecular structure of polymerization product containing phenyl- and diphenylsiloxy units
Hayashida S., Imamura S.
Journal of Polymer Science, Part A: Polymer Chemistry, 1995
26.
10.1016/j.mencom.2019.07.022_bib0100
Andrianov
J. Polym. Sci., Part A: Polym. Chem., 1976
27.
New type of temperature variation of X-ray diffraction from a number of polymers
Tsvankin D.Y., Levin V.Y., Pankov V.S., Zhukov V.P., Zhdanov A.A., Andrianov K.A.
Polymer Science U S S R, 1979
28.
10.1016/j.mencom.2019.07.022_bib0110
Helminiak
Polym. Prepr., 1967
29.
Polyhedral oligomeric silsesquioxanes (POSS) thermal degradation
Fina A., Tabuani D., Carniato F., Frache A., Boccaleri E., Camino G.
Thermochimica Acta, 2006