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Chemically induced symmetry breaking in the crystal structure of guanidinium uranyl sulfate

Vladislav V Gurzhiy 1
Vladislav V Gurzhiy
, 
Olga Sergeevna Tyumentseva 1
Olga Sergeevna Tyumentseva
, 
Olga V Belova 2
Olga V Belova
, 
Sergei Vladimirovich Krivovichev 1, 3
Sergei Vladimirovich Krivovichev
10.1016/j.mencom.2019.07.017
Published 2019-07-01
Communication , Volume 29, Issue 4, 408-410
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Gurzhiy V. V. et al. Chemically induced symmetry breaking in the crystal structure of guanidinium uranyl sulfate // Mendeleev Communications. 2019. Vol. 29. No. 4. pp. 408-410.
GOST all authors (up to 50) Copy
Gurzhiy V. V., Tyumentseva O. S., Belova O. V., Krivovichev S. V. Chemically induced symmetry breaking in the crystal structure of guanidinium uranyl sulfate // Mendeleev Communications. 2019. Vol. 29. No. 4. pp. 408-410.
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TY - JOUR
DO - 10.1016/j.mencom.2019.07.017
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.07.017
TI - Chemically induced symmetry breaking in the crystal structure of guanidinium uranyl sulfate
T2 - Mendeleev Communications
AU - Gurzhiy, Vladislav V
AU - Tyumentseva, Olga Sergeevna
AU - Belova, Olga V
AU - Krivovichev, Sergei Vladimirovich
PY - 2019
DA - 2019/07/01
PB - Mendeleev Communications
SP - 408-410
IS - 4
VL - 29
ER -
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@article{2019_Gurzhiy,
author = {Vladislav V Gurzhiy and Olga Sergeevna Tyumentseva and Olga V Belova and Sergei Vladimirovich Krivovichev},
title = {Chemically induced symmetry breaking in the crystal structure of guanidinium uranyl sulfate},
journal = {Mendeleev Communications},
year = {2019},
volume = {29},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.07.017},
number = {4},
pages = {408--410},
doi = {10.1016/j.mencom.2019.07.017}
}
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Gurzhiy, Vladislav V., et al. “Chemically induced symmetry breaking in the crystal structure of guanidinium uranyl sulfate.” Mendeleev Communications, vol. 29, no. 4, Jul. 2019, pp. 408-410. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.07.017.

Abstract

The novel uranyl sulfate templated by protonated guanidinium molecules was obtained from aqueous solution under ambient conditions. Its crystal structure was determined by the single crystal X-ray diffraction analysis and evaluated using a topological approach and information-based complexity calculations. The Se-for-S substitution resulted in a symmetry breaking (from orthorhombic in sulfate to monoclinic in selenate) due to the rearrangement of oxygen atoms, so the resulting symmetry is a consequence of interplay between the template-substructure interactions and size of the tetrahedral cation.

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