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Disorder–order phase transition in nanocrystalline titanium monoxide with two-sublattice ordering of structural vacancies

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Kostenko M. G., Valeeva A. A. Disorder–order phase transition in nanocrystalline titanium monoxide with two-sublattice ordering of structural vacancies // Mendeleev Communications. 2019. Vol. 29. No. 4. pp. 405-407.
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Kostenko M. G., Valeeva A. A. Disorder–order phase transition in nanocrystalline titanium monoxide with two-sublattice ordering of structural vacancies // Mendeleev Communications. 2019. Vol. 29. No. 4. pp. 405-407.
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TY - JOUR
DO - 10.1016/j.mencom.2019.07.016
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.07.016
TI - Disorder–order phase transition in nanocrystalline titanium monoxide with two-sublattice ordering of structural vacancies
T2 - Mendeleev Communications
AU - Kostenko, Maxim Gennad'evich
AU - Valeeva, Al'bina Ahmetovna
PY - 2019
DA - 2019/07/01
PB - Mendeleev Communications
SP - 405-407
IS - 4
VL - 29
ER -
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@article{2019_Kostenko,
author = {Maxim Gennad'evich Kostenko and Al'bina Ahmetovna Valeeva},
title = {Disorder–order phase transition in nanocrystalline titanium monoxide with two-sublattice ordering of structural vacancies},
journal = {Mendeleev Communications},
year = {2019},
volume = {29},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.07.016},
number = {4},
pages = {405--407},
doi = {10.1016/j.mencom.2019.07.016}
}
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Kostenko, Maxim Gennad'evich, and Al'bina Ahmetovna Valeeva. “Disorder–order phase transition in nanocrystalline titanium monoxide with two-sublattice ordering of structural vacancies.” Mendeleev Communications, vol. 29, no. 4, Jul. 2019, pp. 405-407. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.07.016.

Abstract

Atomic-vacancy ordering was achieved via prolonged annealing of nanocrystalline nonstoichiometric titanium monoxide TiOy possessing the average crystal size of ∼30±10nm in vacuo in the temperature range of 300–1200K. The XRD and HRTEM data revealed the ordering based on the orthorhombic super-structures of M2X3 and M3X2 types (space group Immm), which are derived from the B1 structure of disordered cubic phase of γ-TiO.

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