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Effect of the nature of functional groups grafted on the surface of silica nanoparticles on properties of the hybrid proton-conductive membranes based on N-phosphorylated polybenzimidazole

Anna Aleksandrovna Lysova 1
Anna Aleksandrovna Lysova
, 
Igor Igorevich Ponomarev 2
Igor Igorevich Ponomarev
, 
Andrei Borisovich Yaroslavtsev 1
Andrei Borisovich Yaroslavtsev
10.1016/j.mencom.2019.07.015
Published 2019-07-01
Communication , Volume 29, Issue 4, 403-404
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Lysova A. A., Ponomarev I. I., Yaroslavtsev A. B. Effect of the nature of functional groups grafted on the surface of silica nanoparticles on properties of the hybrid proton-conductive membranes based on N-phosphorylated polybenzimidazole // Mendeleev Communications. 2019. Vol. 29. No. 4. pp. 403-404.
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Lysova A. A., Ponomarev I. I., Yaroslavtsev A. B. Effect of the nature of functional groups grafted on the surface of silica nanoparticles on properties of the hybrid proton-conductive membranes based on N-phosphorylated polybenzimidazole // Mendeleev Communications. 2019. Vol. 29. No. 4. pp. 403-404.
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TY - JOUR
DO - 10.1016/j.mencom.2019.07.015
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.07.015
TI - Effect of the nature of functional groups grafted on the surface of silica nanoparticles on properties of the hybrid proton-conductive membranes based on N-phosphorylated polybenzimidazole
T2 - Mendeleev Communications
AU - Lysova, Anna Aleksandrovna
AU - Ponomarev, Igor Igorevich
AU - Yaroslavtsev, Andrei Borisovich
PY - 2019
DA - 2019/07/01
PB - Mendeleev Communications
SP - 403-404
IS - 4
VL - 29
ER -
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@article{2019_Lysova,
author = {Anna Aleksandrovna Lysova and Igor Igorevich Ponomarev and Andrei Borisovich Yaroslavtsev},
title = {Effect of the nature of functional groups grafted on the surface of silica nanoparticles on properties of the hybrid proton-conductive membranes based on N-phosphorylated polybenzimidazole},
journal = {Mendeleev Communications},
year = {2019},
volume = {29},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.07.015},
number = {4},
pages = {403--404},
doi = {10.1016/j.mencom.2019.07.015}
}
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Lysova, Anna Aleksandrovna, et al. “Effect of the nature of functional groups grafted on the surface of silica nanoparticles on properties of the hybrid proton-conductive membranes based on N-phosphorylated polybenzimidazole.” Mendeleev Communications, vol. 29, no. 4, Jul. 2019, pp. 403-404. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.07.015.

Abstract

New hybrid proton-conductive membranes containing in-corporated silica nanoparticles and modified with various functional groups have been designed, prepared and evaluated for conductive properties. The best conductivity (54mScm−1 at 130°C) was reached for membranes doped with silica (15 wt%) bearing grafted imidazolinopropyl groups that favor additional sorption of phosphoric acid.

References

3.
Proton conductivity of hybrid membranes based on polybenzimidazoles and surface-sulfonated silica
Lysova A.A., Stenina I.A., Volkov A.O., Ponomarev I.I., Yaroslavtsev A.B.
Solid State Ionics, 2019
4.
Synthesis of polymers with protogenic groups by polymer-analogous transformations
Rusanov A.L., Solodova E.A., Bulycheva E.G., Abady M., Voitenkunas V.
Russian Chemical Reviews, 2007
5.
10.1016/j.mencom.2019.07.015_bib0025
Lafitte
2007
6.
Arylphosphonic Acid-Functionalized Polyelectrolytes as Fuel Cell Membrane Material
Bock T., Möhwald H., Mülhaupt R.
Macromolecular Chemistry and Physics, 2007
7.
Yaroslavtsev A.B., Yampolskii Y.P.
Mendeleev Communications, 2014
8.
Silica-related membranes in fuel cell applications: An overview
Ying Y.P., Kamarudin S.K., Masdar M.S.
International Journal of Hydrogen Energy, 2018