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CO2 hydrogenation on Fe-based catalysts doped with potassium in gas phase and under supercritical conditions

Yana Andreevna Pokusaeva 1
Yana Andreevna Pokusaeva
, 
Aleksey Evgenievich Koklin 1
Aleksey Evgenievich Koklin
, 
Valery Vasil'evich Lunin 1, 2
Valery Vasil'evich Lunin
, 
Viktor Ignat'evich Bogdan 1, 2
Viktor Ignat'evich Bogdan
10.1016/j.mencom.2019.07.007
Published 2019-07-01
Communication , Volume 29, Issue 4, 382-384
19
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Pokusaeva Y. A. et al. CO2 hydrogenation on Fe-based catalysts doped with potassium in gas phase and under supercritical conditions // Mendeleev Communications. 2019. Vol. 29. No. 4. pp. 382-384.
GOST all authors (up to 50) Copy
Pokusaeva Y. A., Koklin A. E., Lunin V. V., Bogdan V. I. CO2 hydrogenation on Fe-based catalysts doped with potassium in gas phase and under supercritical conditions // Mendeleev Communications. 2019. Vol. 29. No. 4. pp. 382-384.
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TY - JOUR
DO - 10.1016/j.mencom.2019.07.007
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.07.007
TI - CO2 hydrogenation on Fe-based catalysts doped with potassium in gas phase and under supercritical conditions
T2 - Mendeleev Communications
AU - Pokusaeva, Yana Andreevna
AU - Koklin, Aleksey Evgenievich
AU - Lunin, Valery Vasil'evich
AU - Bogdan, Viktor Ignat'evich
PY - 2019
DA - 2019/07/01
PB - Mendeleev Communications
SP - 382-384
IS - 4
VL - 29
ER -
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@article{2019_Pokusaeva,
author = {Yana Andreevna Pokusaeva and Aleksey Evgenievich Koklin and Valery Vasil'evich Lunin and Viktor Ignat'evich Bogdan},
title = {CO2 hydrogenation on Fe-based catalysts doped with potassium in gas phase and under supercritical conditions},
journal = {Mendeleev Communications},
year = {2019},
volume = {29},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.07.007},
number = {4},
pages = {382--384},
doi = {10.1016/j.mencom.2019.07.007}
}
MLA
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MLA Copy
Pokusaeva, Yana Andreevna, et al. “CO2 hydrogenation on Fe-based catalysts doped with potassium in gas phase and under supercritical conditions.” Mendeleev Communications, vol. 29, no. 4, Jul. 2019, pp. 382-384. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.07.007.

Abstract

New catalysts FeK/Sibunit and FeCuK/Sibunit were prepared and applied for the CO2 hydrogenation in the temperature range of 250–400°C and under the pressures of 1, 20 and 85atm. The reverse water gas shift reaction prevailed under the atmospheric pressure (i.e., CO2 was selectively converted into CO), while the formation of C1–C12 hydrocarbons occurred under the increased pressures. The Cu-containing catalyst exhibited the higher activity and selectivity towards C1–C12 hydrocarbons.

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