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Single-stage synthesis of alkyl-H-phosphinic acids from elemental phosphorus and alkyl bromides

Nina Kuzminichna Gusarova 1
Nina Kuzminichna Gusarova
, 
Anastasiya Olegovna Sutyrina 1
Anastasiya Olegovna Sutyrina
, 
Vladimir Anatol'evich Kuimov 1
Vladimir Anatol'evich Kuimov
, 
Svetlana Filippovna Malysheva 1
Svetlana Filippovna Malysheva
, 
Natalia Alekseevna Belogorlova 1
Natalia Alekseevna Belogorlova
, 
Pavel Anatol'evich Volkov 1
Pavel Anatol'evich Volkov
, 
Boris Aleksandrovich Trofimov 1
Boris Aleksandrovich Trofimov
10.1016/j.mencom.2019.05.030
Published 2019-04-26
Communication , Volume 29, Issue 3, 328-330
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Gusarova N. K. et al. Single-stage synthesis of alkyl-H-phosphinic acids from elemental phosphorus and alkyl bromides // Mendeleev Communications. 2019. Vol. 29. No. 3. pp. 328-330.
GOST all authors (up to 50) Copy
Gusarova N. K., Sutyrina A. O., Kuimov V. A., Malysheva S. F., Belogorlova N. A., Volkov P. A., Trofimov B. A. Single-stage synthesis of alkyl-H-phosphinic acids from elemental phosphorus and alkyl bromides // Mendeleev Communications. 2019. Vol. 29. No. 3. pp. 328-330.
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TY - JOUR
DO - 10.1016/j.mencom.2019.05.030
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.05.030
TI - Single-stage synthesis of alkyl-H-phosphinic acids from elemental phosphorus and alkyl bromides
T2 - Mendeleev Communications
AU - Gusarova, Nina Kuzminichna
AU - Sutyrina, Anastasiya Olegovna
AU - Kuimov, Vladimir Anatol'evich
AU - Malysheva, Svetlana Filippovna
AU - Belogorlova, Natalia Alekseevna
AU - Volkov, Pavel Anatol'evich
AU - Trofimov, Boris Aleksandrovich
PY - 2019
DA - 2019/04/26
PB - Mendeleev Communications
SP - 328-330
IS - 3
VL - 29
ER -
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@article{2019_Gusarova,
author = {Nina Kuzminichna Gusarova and Anastasiya Olegovna Sutyrina and Vladimir Anatol'evich Kuimov and Svetlana Filippovna Malysheva and Natalia Alekseevna Belogorlova and Pavel Anatol'evich Volkov and Boris Aleksandrovich Trofimov},
title = {Single-stage synthesis of alkyl-H-phosphinic acids from elemental phosphorus and alkyl bromides},
journal = {Mendeleev Communications},
year = {2019},
volume = {29},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.05.030},
number = {3},
pages = {328--330},
doi = {10.1016/j.mencom.2019.05.030}
}
MLA
Cite this
MLA Copy
Gusarova, Nina Kuzminichna, et al. “Single-stage synthesis of alkyl-H-phosphinic acids from elemental phosphorus and alkyl bromides.” Mendeleev Communications, vol. 29, no. 3, Apr. 2019, pp. 328-330. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.05.030.

Abstract

Elemental phosphorus (red or white) reacts with alkyl bromides at 60–62°C in the phase-transfer catalytic system KOH/H2O/PhMe/Et3BnNCl to afford alkyl-H-phosphinic acids in up to 47% yield.

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