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Electrocatalytic properties of a Pd0(Pb) composite synthesized by galvanic displacement: activity towards formic acid oxidation

Boris Ivanovich Podlovchenko 1
Boris Ivanovich Podlovchenko
, 
Yurii Mikailovich Maksimov 1
Yurii Mikailovich Maksimov
, 
10.1016/j.mencom.2019.05.024
Published 2019-04-26
Communication , Volume 29, Issue 3, 312-314
3
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Podlovchenko B. I., Maksimov Y. M., Shkil D. O. Electrocatalytic properties of a Pd0(Pb) composite synthesized by galvanic displacement: activity towards formic acid oxidation // Mendeleev Communications. 2019. Vol. 29. No. 3. pp. 312-314.
GOST all authors (up to 50) Copy
Podlovchenko B. I., Maksimov Y. M., Shkil D. O. Electrocatalytic properties of a Pd0(Pb) composite synthesized by galvanic displacement: activity towards formic acid oxidation // Mendeleev Communications. 2019. Vol. 29. No. 3. pp. 312-314.
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TY - JOUR
DO - 10.1016/j.mencom.2019.05.024
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.05.024
TI - Electrocatalytic properties of a Pd0(Pb) composite synthesized by galvanic displacement: activity towards formic acid oxidation
T2 - Mendeleev Communications
AU - Podlovchenko, Boris Ivanovich
AU - Maksimov, Yurii Mikailovich
AU - Shkil, Dmitry Olegovich
PY - 2019
DA - 2019/04/26
PB - Mendeleev Communications
SP - 312-314
IS - 3
VL - 29
ER -
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@article{2019_Podlovchenko,
author = {Boris Ivanovich Podlovchenko and Yurii Mikailovich Maksimov and Dmitry Olegovich Shkil},
title = {Electrocatalytic properties of a Pd0(Pb) composite synthesized by galvanic displacement: activity towards formic acid oxidation},
journal = {Mendeleev Communications},
year = {2019},
volume = {29},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.05.024},
number = {3},
pages = {312--314},
doi = {10.1016/j.mencom.2019.05.024}
}
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Podlovchenko, Boris Ivanovich, et al. “Electrocatalytic properties of a Pd0(Pb) composite synthesized by galvanic displacement: activity towards formic acid oxidation.” Mendeleev Communications, vol. 29, no. 3, Apr. 2019, pp. 312-314. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.05.024.

Abstract

Galvanic displacement of electrodeposited lead by palladium fails to produce Pd shells. The anomalous ratio between formic acid electrooxidation reaction (FAOR) rates on Pd0(Pb) observed in HClO4 and H2SO4 solutions is associated with the reduction of ClO4− anions to chloride ones which inhibit the FAOR.

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