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Nucleophilic substitution of hydrogen–the Boger reaction sequence as an approach towards 8-(pyridin-2-yl)coumarins

Ramil Faatovich Fatykhov 1
Ramil Faatovich Fatykhov
, 
Maria Igorevna Savchuk 1
Maria Igorevna Savchuk
,  , 
Maria Vladimirovna Bobkina 1
Maria Vladimirovna Bobkina
, 
Dmitrii Sergeevich Kopchuk 1, 2
Dmitrii Sergeevich Kopchuk
, 
Emiliya Vladimirovna Nosova 1, 2
Emiliya Vladimirovna Nosova
, 
Grigory Vasil'evich Zyryanov 1, 2
Grigory Vasil'evich Zyryanov
, 
Igor Alekseevich Khalymbadzha 1, 2
Igor Alekseevich Khalymbadzha
, 
Oleg Nikolaevich Chupakhin 1, 2
Oleg Nikolaevich Chupakhin
, 
Valery Nikolaevich Charushin 1, 2
Valery Nikolaevich Charushin
, 
Victor Georgievich Kartsev 3
Victor Georgievich Kartsev
10.1016/j.mencom.2019.05.019
Published 2019-04-26
Communication , Volume 29, Issue 3, 299-300
26
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Fatykhov R. F. et al. Nucleophilic substitution of hydrogen–the Boger reaction sequence as an approach towards 8-(pyridin-2-yl)coumarins // Mendeleev Communications. 2019. Vol. 29. No. 3. pp. 299-300.
GOST all authors (up to 50) Copy
Fatykhov R. F., Savchuk M. I., Starnovskaya E. S., Bobkina M. V., Kopchuk D. S., Nosova E. V., Zyryanov G. V., Khalymbadzha I. A., Chupakhin O. N., Charushin V. N., Kartsev V. G. Nucleophilic substitution of hydrogen–the Boger reaction sequence as an approach towards 8-(pyridin-2-yl)coumarins // Mendeleev Communications. 2019. Vol. 29. No. 3. pp. 299-300.
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TY - JOUR
DO - 10.1016/j.mencom.2019.05.019
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.05.019
TI - Nucleophilic substitution of hydrogen–the Boger reaction sequence as an approach towards 8-(pyridin-2-yl)coumarins
T2 - Mendeleev Communications
AU - Fatykhov, Ramil Faatovich
AU - Savchuk, Maria Igorevna
AU - Starnovskaya, Ekaterina S
AU - Bobkina, Maria Vladimirovna
AU - Kopchuk, Dmitrii Sergeevich
AU - Nosova, Emiliya Vladimirovna
AU - Zyryanov, Grigory Vasil'evich
AU - Khalymbadzha, Igor Alekseevich
AU - Chupakhin, Oleg Nikolaevich
AU - Charushin, Valery Nikolaevich
AU - Kartsev, Victor Georgievich
PY - 2019
DA - 2019/04/26
PB - Mendeleev Communications
SP - 299-300
IS - 3
VL - 29
ER -
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@article{2019_Fatykhov,
author = {Ramil Faatovich Fatykhov and Maria Igorevna Savchuk and Ekaterina S Starnovskaya and Maria Vladimirovna Bobkina and Dmitrii Sergeevich Kopchuk and Emiliya Vladimirovna Nosova and Grigory Vasil'evich Zyryanov and Igor Alekseevich Khalymbadzha and Oleg Nikolaevich Chupakhin and Valery Nikolaevich Charushin and Victor Georgievich Kartsev},
title = {Nucleophilic substitution of hydrogen–the Boger reaction sequence as an approach towards 8-(pyridin-2-yl)coumarins},
journal = {Mendeleev Communications},
year = {2019},
volume = {29},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.05.019},
number = {3},
pages = {299--300},
doi = {10.1016/j.mencom.2019.05.019}
}
MLA
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Fatykhov, Ramil Faatovich, et al. “Nucleophilic substitution of hydrogen–the Boger reaction sequence as an approach towards 8-(pyridin-2-yl)coumarins.” Mendeleev Communications, vol. 29, no. 3, Apr. 2019, pp. 299-300. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.05.019.
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Abstract

5,7-Dimethoxy-8-(3,6-diphenylpyridin-2-yl)coumarins were obtained from 5,7-dimethoxycoumarins and 3,6-diphenyl-1,2,4-triazines via the protocol comprising aromatic \( \mathrm{S_N^H} \) substitution in the triazine ring followed by the Boger transformation of formed triazine moiety into the pyridine one. The advantages of the suggested method are simple procedures, high yields, and the absence of transition-metal catalysts.

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