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Arylglyoxal oximes as putative C-nucleophiles in eliminative nucleophilic substitution process

Dmitry Vadimovich Tsyganov 1
Dmitry Vadimovich Tsyganov
, 
Alexander Viktorovich Samet 1
Alexander Viktorovich Samet
, 
Pavel Vladimirovich Dorovatovskii 2
Pavel Vladimirovich Dorovatovskii
, 
Victor Nikolaevich Khrustalev 2, 3
Victor Nikolaevich Khrustalev
, 
Victor Vladimirovich Semenov 1
Victor Vladimirovich Semenov
10.1016/j.mencom.2019.05.018
Published 2019-04-26
Communication , Volume 29, Issue 3, 296-298
3
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Tsyganov D. V. et al. Arylglyoxal oximes as putative C-nucleophiles in eliminative nucleophilic substitution process // Mendeleev Communications. 2019. Vol. 29. No. 3. pp. 296-298.
GOST all authors (up to 50) Copy
Tsyganov D. V., Samet A. V., Dorovatovskii P. V., Khrustalev V. N., Semenov V. V. Arylglyoxal oximes as putative C-nucleophiles in eliminative nucleophilic substitution process // Mendeleev Communications. 2019. Vol. 29. No. 3. pp. 296-298.
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TY - JOUR
DO - 10.1016/j.mencom.2019.05.018
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.05.018
TI - Arylglyoxal oximes as putative C-nucleophiles in eliminative nucleophilic substitution process
T2 - Mendeleev Communications
AU - Tsyganov, Dmitry Vadimovich
AU - Samet, Alexander Viktorovich
AU - Dorovatovskii, Pavel Vladimirovich
AU - Khrustalev, Victor Nikolaevich
AU - Semenov, Victor Vladimirovich
PY - 2019
DA - 2019/04/26
PB - Mendeleev Communications
SP - 296-298
IS - 3
VL - 29
ER -
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@article{2019_Tsyganov,
author = {Dmitry Vadimovich Tsyganov and Alexander Viktorovich Samet and Pavel Vladimirovich Dorovatovskii and Victor Nikolaevich Khrustalev and Victor Vladimirovich Semenov},
title = {Arylglyoxal oximes as putative C-nucleophiles in eliminative nucleophilic substitution process},
journal = {Mendeleev Communications},
year = {2019},
volume = {29},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.05.018},
number = {3},
pages = {296--298},
doi = {10.1016/j.mencom.2019.05.018}
}
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Tsyganov, Dmitry Vadimovich, et al. “Arylglyoxal oximes as putative C-nucleophiles in eliminative nucleophilic substitution process.” Mendeleev Communications, vol. 29, no. 3, Apr. 2019, pp. 296-298. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.05.018.

Abstract

Reaction of arylglyoxal oximes ArCOCH=NOH (Ar=4-MeOC6H4, Ph) with 5-arylfurazanopyrazines proceeds as vicarious nucleophilic substitution of hydrogen in pyrazine ring with the elimination of hyponitrous acid, affording 5-(aroylmethylidene)-6-aryl-4H-furazano[3,4-b]pyrazines. Structure of the product was confirmed by X-ray diffraction.

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