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New preparative Grignard synthesis of (m-carboranylmethyl)siloxanes from chlorodimethylsiloxanes

Boris Aleksandrovich Izmaylov 1
Boris Aleksandrovich Izmaylov
, 
Valery Aleksandrovich Vasnev 1
Valery Aleksandrovich Vasnev
, 
10.1016/j.mencom.2019.03.026
Published 2019-03-01
Communication , Volume 29, Issue 2, 194-195
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Izmaylov B. A., Vasnev V. A., Markova G. D. New preparative Grignard synthesis of (m-carboranylmethyl)siloxanes from chlorodimethylsiloxanes // Mendeleev Communications. 2019. Vol. 29. No. 2. pp. 194-195.
GOST all authors (up to 50) Copy
Izmaylov B. A., Vasnev V. A., Markova G. D. New preparative Grignard synthesis of (m-carboranylmethyl)siloxanes from chlorodimethylsiloxanes // Mendeleev Communications. 2019. Vol. 29. No. 2. pp. 194-195.
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TY - JOUR
DO - 10.1016/j.mencom.2019.03.026
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.03.026
TI - New preparative Grignard synthesis of (m-carboranylmethyl)siloxanes from chlorodimethylsiloxanes
T2 - Mendeleev Communications
AU - Izmaylov, Boris Aleksandrovich
AU - Vasnev, Valery Aleksandrovich
AU - Markova, Gali Dmitrievna
PY - 2019
DA - 2019/03/01
PB - Mendeleev Communications
SP - 194-195
IS - 2
VL - 29
ER -
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@article{2019_Izmaylov,
author = {Boris Aleksandrovich Izmaylov and Valery Aleksandrovich Vasnev and Gali Dmitrievna Markova},
title = {New preparative Grignard synthesis of (m-carboranylmethyl)siloxanes from chlorodimethylsiloxanes},
journal = {Mendeleev Communications},
year = {2019},
volume = {29},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.03.026},
number = {2},
pages = {194--195},
doi = {10.1016/j.mencom.2019.03.026}
}
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Izmaylov, Boris Aleksandrovich, et al. “New preparative Grignard synthesis of (m-carboranylmethyl)siloxanes from chlorodimethylsiloxanes.” Mendeleev Communications, vol. 29, no. 2, Mar. 2019, pp. 194-195. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.03.026.

Abstract

New m-carborane-containing siloxanes were obtained by the Grignard reaction based on chloromethyl-m-carboranes and chlorodimethylsiloxanes. In case of (7-methyl-m-carboran-1-yl)methyl chloride, side processes of isomerization and transmetalation do not occur, which provides the yield of the desired product as high as 87%.

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