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Phosphorylation of (1-aryl-1-hydroxymethyl)phosphonates

Zita Radai 1
Zita Radai
, 
Viktória Hodula 1
Viktória Hodula
, 
Nóra Zsuzsa Kiss 1
Nóra Zsuzsa Kiss
, 
János Koti 2
János Koti
, 
2 Spectroscopic Research Division, Gedeon Richter Plc., Budapest, Hungary
10.1016/j.mencom.2019.03.011
Published 2019-03-01
Communication , Volume 29, Issue 2, 153-154
15
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Radai Z. et al. Phosphorylation of (1-aryl-1-hydroxymethyl)phosphonates // Mendeleev Communications. 2019. Vol. 29. No. 2. pp. 153-154.
GOST all authors (up to 50) Copy
Radai Z., Hodula V., Kiss N. Z., Koti J., Keglevich G. T. Phosphorylation of (1-aryl-1-hydroxymethyl)phosphonates // Mendeleev Communications. 2019. Vol. 29. No. 2. pp. 153-154.
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TY - JOUR
DO - 10.1016/j.mencom.2019.03.011
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.03.011
TI - Phosphorylation of (1-aryl-1-hydroxymethyl)phosphonates
T2 - Mendeleev Communications
AU - Radai, Zita
AU - Hodula, Viktória
AU - Kiss, Nóra Zsuzsa
AU - Koti, János
AU - Keglevich, György Tibor
PY - 2019
DA - 2019/03/01
PB - Mendeleev Communications
SP - 153-154
IS - 2
VL - 29
ER -
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@article{2019_Radai,
author = {Zita Radai and Viktória Hodula and Nóra Zsuzsa Kiss and János Koti and György Tibor Keglevich},
title = {Phosphorylation of (1-aryl-1-hydroxymethyl)phosphonates},
journal = {Mendeleev Communications},
year = {2019},
volume = {29},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.03.011},
number = {2},
pages = {153--154},
doi = {10.1016/j.mencom.2019.03.011}
}
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Radai, Zita, et al. “Phosphorylation of (1-aryl-1-hydroxymethyl)phosphonates.” Mendeleev Communications, vol. 29, no. 2, Mar. 2019, pp. 153-154. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.03.011.
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Abstract

The reaction of dimethyl (1-aryl-1-hydroxymethyl)phosphonates with 1-chloro-3-phospholene 1-oxides, diphenylphosphinic chloride or diphenyl chloridophosphonate affords the corresponding (1-phosphoryloxymethyl)phosphonates. The products with two different >P(O)– moieties exhibit characteristic δP shifts and 3JP,P couplings in the 31P NMR spectra.

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