Home / Publications / Non-covalent interactions in stoichiometric and catalytic reactions of iridium pincer complexes

Non-covalent interactions in stoichiometric and catalytic reactions of iridium pincer complexes

Elena Sergeevna Osipova 1
Elena Sergeevna Osipova
,  ,  , 
Natalia Viktorovna Belkova 1
Natalia Viktorovna Belkova
10.1016/j.mencom.2019.03.001
Published 2019-03-01
Focus article , Volume 29, Issue 2, 121-127
6
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Osipova E. S. et al. Non-covalent interactions in stoichiometric and catalytic reactions of iridium pincer complexes // Mendeleev Communications. 2019. Vol. 29. No. 2. pp. 121-127.
GOST all authors (up to 50) Copy
Osipova E. S., Filippov O. A., Shubina E. S., Belkova N. V. Non-covalent interactions in stoichiometric and catalytic reactions of iridium pincer complexes // Mendeleev Communications. 2019. Vol. 29. No. 2. pp. 121-127.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2019.03.001
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.03.001
TI - Non-covalent interactions in stoichiometric and catalytic reactions of iridium pincer complexes
T2 - Mendeleev Communications
AU - Osipova, Elena Sergeevna
AU - Filippov, Oleg Andreevich
AU - Shubina, Elena Solomonovna
AU - Belkova, Natalia Viktorovna
PY - 2019
DA - 2019/03/01
PB - Mendeleev Communications
SP - 121-127
IS - 2
VL - 29
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2019_Osipova,
author = {Elena Sergeevna Osipova and Oleg Andreevich Filippov and Elena Solomonovna Shubina and Natalia Viktorovna Belkova},
title = {Non-covalent interactions in stoichiometric and catalytic reactions of iridium pincer complexes},
journal = {Mendeleev Communications},
year = {2019},
volume = {29},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.03.001},
number = {2},
pages = {121--127},
doi = {10.1016/j.mencom.2019.03.001}
}
MLA
Cite this
MLA Copy
Osipova, Elena Sergeevna, et al. “Non-covalent interactions in stoichiometric and catalytic reactions of iridium pincer complexes.” Mendeleev Communications, vol. 29, no. 2, Mar. 2019, pp. 121-127. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.03.001.
Views / Downloads
1 / 5

Abstract

Recent results in the chemistry of various pincer IrIII complexes are highlighted with the particular attention paid to the activation of Ir–Cl and Z–H bonds (Z–H=M–H, B–H, N–H, etc.) via low-energy (non-covalent) interactions (hydrogen bonded or Lewis complexes) and the role of such interactions in the proposed mechanisms of amine–borane dehydrogenation reaction.

References

1.
Hydrogen and Dihydrogen Bonds in the Reactions of Metal Hydrides
Belkova N.V., Epstein L.M., Filippov O.A., Shubina E.S.
Chemical Reviews, 2016
2.
Chemistry of boron hydrides orchestrated by dihydrogen bonds
Filippov O.A., Belkova N.V., Epstein L.M., Shubina E.S.
Journal of Organometallic Chemistry, 2013
3.
Dihydrogen Bonding, Proton Transfer and Beyond: What We Can Learn from Kinetics and Thermodynamics
Belkova N.V., Epstein L.M., Shubina E.S.
European Journal of Inorganic Chemistry, 2010
4.
Z-H Bond Activation in (Di)hydrogen Bonding as a Way to Proton/Hydride Transfer and H2 Evolution.
Belkova N.V., Filippov O.A., Shubina E.S.
Chemistry - A European Journal, 2017
6.
Unravelling the Mechanism of the Asymmetric Hydrogenation of Acetophenone by [RuX2(diphosphine)(1,2-diamine)] Catalysts
Dub P.A., Henson N.J., Martin R.L., Gordon J.C.
Journal of the American Chemical Society, 2014
7.
10.1016/j.mencom.2019.03.001_bib0035
Handbook of Hydrogen Energy, 2014
8.
Boron–nitrogen based hydrides and reactive composites for hydrogen storage
Jepsen L.H., Ley M.B., Lee Y., Cho Y.W., Dornheim M., Jensen J.O., Filinchuk Y., Jørgensen J.E., Besenbacher F., Jensen T.R.
Materials Today, 2014
9.
Ammonia-Borane and Related Compounds as Dihydrogen Sources
Staubitz A., Robertson A.P., Manners I.
Chemical Reviews, 2010
10.
Porous boron nitride nanosheets for effective water cleaning
Lei W., Portehault D., Liu D., Qin S., Chen Y.
Nature Communications, 2013
12.
Regeneration of ammonia borane from spent fuel materials
Summerscales O.T., Gordon J.C.
Dalton Transactions, 2013
13.
10.1016/j.mencom.2019.03.001_bib0065
Johnson
Synthesis and Application of Organoboron Compounds, 2015
15.
Catalytic Dehydrocoupling of Amine–Boranes using Cationic Zirconium(IV)–Phosphine Frustrated Lewis Pairs
Metters O.J., Flynn S.R., Dowds C.K., Sparkes H.A., Manners I., Wass D.F.
ACS Catalysis, 2016
16.
Catalysis and Mechanism of H2 Release from Amine-Boranes by Diiron Complexes
Lunsford A.M., Blank J.H., Moncho S., Haas S.C., Muhammad S., Brothers E.N., Darensbourg M.Y., Bengali A.A.
Inorganic Chemistry, 2015
19.
Efficient catalysis of ammonia borane dehydrogenation.
Denney M.C., Pons V., Hebden T.J., Heinekey D.M., Goldberg K.I.
Journal of the American Chemical Society, 2006
22.
Alkane Metathesis by Tandem Alkane-Dehydrogenation–Olefin-Metathesis Catalysis and Related Chemistry
Haibach M.C., Kundu S., Brookhart M., Goldman A.S.
Accounts of Chemical Research, 2012
23.
Dehydrogenation and Related Reactions Catalyzed by Iridium Pincer Complexes
Choi J., MacArthur A.H., Brookhart M., Goldman A.S.
Chemical Reviews, 2011
24.
PCP Pincer Iridium Chemistry – Coordination of Pyridines to [(tBuPCP)IrH(Cl)]
Titova E.M., Silantyev G.A., Filippov O.A., Gulyaeva E.S., Gutsul E.I., Dolgushin F.M., Belkova N.V.
European Journal of Inorganic Chemistry, 2015
25.
Mild activation of IrCl bond upon the interaction of pincer iridium hydride (tBuPCP)IrH(Cl) with acids and bases
Titova E.M., Osipova E.S., Gulyaeva E.S., Torocheshnikov V.N., Pavlov A.A., Silantyev G.A., Filippov O.A., Shubina E.S., Belkova N.V.
Journal of Organometallic Chemistry, 2017
26.
Mechanism of Dimethylamine–Borane Dehydrogenation Catalyzed by an Iridium(III) PCP-Pincer Complex
Titova E.M., Osipova E.S., Pavlov A.A., Filippov O.A., Safronov S.V., Shubina E.S., Belkova N.V.
ACS Catalysis, 2017
28.
A novel functionalized P,C,P pincer ligand complex
Grimm J.C., Nachtigal C., Mack H.-., Kaska W.C., Mayer H.A.
Inorganic Chemistry Communication, 2000
29.
Amine Boranes Dehydrogenation Mediated by an Unsymmetrical Iridium Pincer Hydride: (PCN) vs (PCP) Improved Catalytic Performance
Luconi L., Osipova E.S., Giambastiani G., Peruzzini M., Rossin A., Belkova N.V., Filippov O.A., Titova E.M., Pavlov A.A., Shubina E.S.
Organometallics, 2018
32.
Iridium(iii) hydrido complexes for the catalytic dehydrogenation of hydrazine borane.
Han D., Joksch M., Klahn M., Spannenberg A., Drexler H.-., Baumann W., Jiao H., Knitsch R., Hansen M.R., Eckert H., Beweries T.
Dalton Transactions, 2016
34.
Effect of Ligands on the Lewis Acidity of the Metal and the Binding of N-Bases to Iridium Pincer Complexes
Osipova E.S., Gulyaeva E.S., Filippov O.A., Safronov S.V., Pavlov A.A., Polukeev A.V., Kirkina V.A., Titova E.M., Shubina E.S., Belkova N.V.
European Journal of Inorganic Chemistry, 2019
37.
Syntheses of PBP pincer iridium complexes: a supporting boryl ligand.
Segawa Y., Yamashita M., Nozaki K.
Journal of the American Chemical Society, 2009
39.
Multiple metal-bound oligomers from Ir-catalysed dehydropolymerisation of H3B·NH3 as probed by experiment and computation
Kumar A., Johnson H.C., Hooper T.N., Weller A.S., Algarra A.G., Macgregor S.A.
Chemical Science, 2014