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Modified synthesis of Ru–Rh heterobimetallic metallacarboranes based on ruthenium exo-nido complexes and not accompanied by exo-nido → closo rearrangement

Dmitrii Ilyich D'yachikhin 1
Dmitrii Ilyich D'yachikhin
, 
Alexander Yur'evich Kostyukovich 2
Alexander Yur'evich Kostyukovich
, 
Ivan Alexandrovich Godovikov 1
Ivan Alexandrovich Godovikov
, 
Alexander Petrovich Molotkov 1
Alexander Petrovich Molotkov
, 
Elena Vladimirovna Balagurova 1
Elena Vladimirovna Balagurova
, 
Igor Timofeevich Chizhevsky 1
Igor Timofeevich Chizhevsky
10.1016/j.mencom.2019.01.023
Published 2018-12-28
Communication , Volume 29, Issue 1, 69-70
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D'yachikhin D. I. et al. Modified synthesis of Ru–Rh heterobimetallic metallacarboranes based on ruthenium exo-nido complexes and not accompanied by exo-nido → closo rearrangement // Mendeleev Communications. 2018. Vol. 29. No. 1. pp. 69-70.
GOST all authors (up to 50) Copy
D'yachikhin D. I., Kostyukovich A. Y., Godovikov I. A., Molotkov A. P., Balagurova E. V., Chizhevsky I. T. Modified synthesis of Ru–Rh heterobimetallic metallacarboranes based on ruthenium exo-nido complexes and not accompanied by exo-nido → closo rearrangement // Mendeleev Communications. 2018. Vol. 29. No. 1. pp. 69-70.
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TY - JOUR
DO - 10.1016/j.mencom.2019.01.023
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.01.023
TI - Modified synthesis of Ru–Rh heterobimetallic metallacarboranes based on ruthenium exo-nido complexes and not accompanied by exo-nido → closo rearrangement
T2 - Mendeleev Communications
AU - D'yachikhin, Dmitrii Ilyich
AU - Kostyukovich, Alexander Yur'evich
AU - Godovikov, Ivan Alexandrovich
AU - Molotkov, Alexander Petrovich
AU - Balagurova, Elena Vladimirovna
AU - Chizhevsky, Igor Timofeevich
PY - 2018
DA - 2018/12/28
PB - Mendeleev Communications
SP - 69-70
IS - 1
VL - 29
ER -
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@article{2018_D'yachikhin,
author = {Dmitrii Ilyich D'yachikhin and Alexander Yur'evich Kostyukovich and Ivan Alexandrovich Godovikov and Alexander Petrovich Molotkov and Elena Vladimirovna Balagurova and Igor Timofeevich Chizhevsky},
title = {Modified synthesis of Ru–Rh heterobimetallic metallacarboranes based on ruthenium exo-nido complexes and not accompanied by exo-nido → closo rearrangement},
journal = {Mendeleev Communications},
year = {2018},
volume = {29},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.01.023},
number = {1},
pages = {69--70},
doi = {10.1016/j.mencom.2019.01.023}
}
MLA
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D'yachikhin, Dmitrii Ilyich, et al. “Modified synthesis of Ru–Rh heterobimetallic metallacarboranes based on ruthenium exo-nido complexes and not accompanied by exo-nido → closo rearrangement.” Mendeleev Communications, vol. 29, no. 1, Dec. 2018, pp. 69-70. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.01.023.

Abstract

The use of improved protocol for the reaction of rhodium acetylacetonate complexes (diene)RhAcac [diene is 1,5-cyclooctadiene or norbornadiene] with exo-nido-ruthenacarboranes 5,6,10-[RuCl(PPh3)2]-5,6,10-(μ-H)3-10-H-7,8-R2-7,8-C2B8H6 (R = H or Me) allowed us to synthesize three new binuclear complexes, wherein the ruthenium atom preserved exo-position and the rhodium-containing moiety coordinated to the open pentagonal face of exo-nido-complex. In addition, one known bimetallacarborane was also prepared for the evaluation of synthetic efficiency of the new procedure.

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