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Diastereoselective vinylogous Mannich reaction of perfluoroalkylated cyclic imines with 2-trimethylsilyloxyfuran

Olga I Shmatova 1
Olga I Shmatova
, 
Valentin Georgievich Nenajdenko 1
Valentin Georgievich Nenajdenko
10.1016/j.mencom.2019.01.018
Published 2018-01-28
Communication , Volume 29, Issue 1, 57-58
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Shmatova O. I., Nenajdenko V. G. Diastereoselective vinylogous Mannich reaction of perfluoroalkylated cyclic imines with 2-trimethylsilyloxyfuran // Mendeleev Communications. 2018. Vol. 29. No. 1. pp. 57-58.
GOST all authors (up to 50) Copy
Shmatova O. I., Nenajdenko V. G. Diastereoselective vinylogous Mannich reaction of perfluoroalkylated cyclic imines with 2-trimethylsilyloxyfuran // Mendeleev Communications. 2018. Vol. 29. No. 1. pp. 57-58.
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TY - JOUR
DO - 10.1016/j.mencom.2019.01.018
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.01.018
TI - Diastereoselective vinylogous Mannich reaction of perfluoroalkylated cyclic imines with 2-trimethylsilyloxyfuran
T2 - Mendeleev Communications
AU - Shmatova, Olga I
AU - Nenajdenko, Valentin Georgievich
PY - 2018
DA - 2018/01/28
PB - Mendeleev Communications
SP - 57-58
IS - 1
VL - 29
ER -
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@article{2018_Shmatova,
author = {Olga I Shmatova and Valentin Georgievich Nenajdenko},
title = {Diastereoselective vinylogous Mannich reaction of perfluoroalkylated cyclic imines with 2-trimethylsilyloxyfuran},
journal = {Mendeleev Communications},
year = {2018},
volume = {29},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.01.018},
number = {1},
pages = {57--58},
doi = {10.1016/j.mencom.2019.01.018}
}
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Shmatova, Olga I., and Valentin Georgievich Nenajdenko. “Diastereoselective vinylogous Mannich reaction of perfluoroalkylated cyclic imines with 2-trimethylsilyloxyfuran.” Mendeleev Communications, vol. 29, no. 1, Jan. 2018, pp. 57-58. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.01.018.

Abstract

The reaction between 2-trimethylsilyloxyfuran and perfluoroalkylated cyclic ketimines with different ring sizes affords 5-(2-perfluoroalkyl-1-azacycloalk-2-yl)furan-2(5H)-ones in yields up to 89% and with excellent rel-(R,R)-diastereoselectivity.

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