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Solvent-free silica gel mediated decarboxylation of C–O coupling products of β-diketones and β-oxo esters with malonyl peroxides

Oleg Vadimovich Bityukov 1, 2
Oleg Vadimovich Bityukov
, 
Vera Andreevna Vil' 1, 2, 3
Vera Andreevna Vil'
, 
Nikita Vladislavovich Lukashin 1, 3
Nikita Vladislavovich Lukashin
, 
Alexander Genrihovich Cherednichenko 4
Alexander Genrihovich Cherednichenko
, 
Gennady Ivanovich Nikishin 1
Gennady Ivanovich Nikishin
, 
Alexander Olegovich Terent'ev 1, 2, 3
Alexander Olegovich Terent'ev
10.1016/j.mencom.2019.01.017
Published 2018-12-28
Communication , Volume 29, Issue 1, 55-56
2
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Bityukov O. V. et al. Solvent-free silica gel mediated decarboxylation of C–O coupling products of β-diketones and β-oxo esters with malonyl peroxides // Mendeleev Communications. 2018. Vol. 29. No. 1. pp. 55-56.
GOST all authors (up to 50) Copy
Bityukov O. V., Vil' V. A., Lukashin N. V., Cherednichenko A. G., Nikishin G. I., Terent'ev A. O. Solvent-free silica gel mediated decarboxylation of C–O coupling products of β-diketones and β-oxo esters with malonyl peroxides // Mendeleev Communications. 2018. Vol. 29. No. 1. pp. 55-56.
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TY - JOUR
DO - 10.1016/j.mencom.2019.01.017
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.01.017
TI - Solvent-free silica gel mediated decarboxylation of C–O coupling products of β-diketones and β-oxo esters with malonyl peroxides
T2 - Mendeleev Communications
AU - Bityukov, Oleg Vadimovich
AU - Vil', Vera Andreevna
AU - Lukashin, Nikita Vladislavovich
AU - Cherednichenko, Alexander Genrihovich
AU - Nikishin, Gennady Ivanovich
AU - Terent'ev, Alexander Olegovich
PY - 2018
DA - 2018/12/28
PB - Mendeleev Communications
SP - 55-56
IS - 1
VL - 29
ER -
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@article{2018_Bityukov,
author = {Oleg Vadimovich Bityukov and Vera Andreevna Vil' and Nikita Vladislavovich Lukashin and Alexander Genrihovich Cherednichenko and Gennady Ivanovich Nikishin and Alexander Olegovich Terent'ev},
title = {Solvent-free silica gel mediated decarboxylation of C–O coupling products of β-diketones and β-oxo esters with malonyl peroxides},
journal = {Mendeleev Communications},
year = {2018},
volume = {29},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.01.017},
number = {1},
pages = {55--56},
doi = {10.1016/j.mencom.2019.01.017}
}
MLA
Cite this
MLA Copy
Bityukov, Oleg Vadimovich, et al. “Solvent-free silica gel mediated decarboxylation of C–O coupling products of β-diketones and β-oxo esters with malonyl peroxides.” Mendeleev Communications, vol. 29, no. 1, Dec. 2018, pp. 55-56. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.01.017.

Abstract

Silica gel was found to mediate decarboxylation of tetracarbonyl compounds with a free carboxylic group prepared from β-dicarbonyl compounds and malonyl peroxides. Under solvent-free heterogeneous conditions silica gel effectively acts as a mediator of C–O coupling with further decarboxylation at 120°C.

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