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Novel 2-alkoxy- and 2-alkylthio-substituted pyrimidines containing 2-(1-methyl-1H-pyrrol-2-yl)vinyl moieties: optical and electrochemical properties

Ekaterina Andreevna Komissarova 1, 2
Ekaterina Andreevna Komissarova
, 
Maksim Victorovich Dmitriev 2
Maksim Victorovich Dmitriev
, 
Ivan Gennad'evich Mokrushin 2
Ivan Gennad'evich Mokrushin
, 
Aleksandr Nikolaevich Vasyanin 2
Aleksandr Nikolaevich Vasyanin
, 
Igor Vladimirovich Lunegov 2
Igor Vladimirovich Lunegov
, 
Elena Victorovna Shklyaeva 2
Elena Victorovna Shklyaeva
, 
Georgii Georgievich Abashev 1, 2
Georgii Georgievich Abashev
10.1016/j.mencom.2019.01.014
Published 2018-12-28
Communication , Volume 29, Issue 1, 47-49
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Komissarova E. A. et al. Novel 2-alkoxy- and 2-alkylthio-substituted pyrimidines containing 2-(1-methyl-1H-pyrrol-2-yl)vinyl moieties: optical and electrochemical properties // Mendeleev Communications. 2018. Vol. 29. No. 1. pp. 47-49.
GOST all authors (up to 50) Copy
Komissarova E. A., Dmitriev M. V., Mokrushin I. G., Vasyanin A. N., Lunegov I. V., Shklyaeva E. V., Abashev G. G. Novel 2-alkoxy- and 2-alkylthio-substituted pyrimidines containing 2-(1-methyl-1H-pyrrol-2-yl)vinyl moieties: optical and electrochemical properties // Mendeleev Communications. 2018. Vol. 29. No. 1. pp. 47-49.
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TY - JOUR
DO - 10.1016/j.mencom.2019.01.014
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.01.014
TI - Novel 2-alkoxy- and 2-alkylthio-substituted pyrimidines containing 2-(1-methyl-1H-pyrrol-2-yl)vinyl moieties: optical and electrochemical properties
T2 - Mendeleev Communications
AU - Komissarova, Ekaterina Andreevna
AU - Dmitriev, Maksim Victorovich
AU - Mokrushin, Ivan Gennad'evich
AU - Vasyanin, Aleksandr Nikolaevich
AU - Lunegov, Igor Vladimirovich
AU - Shklyaeva, Elena Victorovna
AU - Abashev, Georgii Georgievich
PY - 2018
DA - 2018/12/28
PB - Mendeleev Communications
SP - 47-49
IS - 1
VL - 29
ER -
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@article{2018_Komissarova,
author = {Ekaterina Andreevna Komissarova and Maksim Victorovich Dmitriev and Ivan Gennad'evich Mokrushin and Aleksandr Nikolaevich Vasyanin and Igor Vladimirovich Lunegov and Elena Victorovna Shklyaeva and Georgii Georgievich Abashev},
title = {Novel 2-alkoxy- and 2-alkylthio-substituted pyrimidines containing 2-(1-methyl-1H-pyrrol-2-yl)vinyl moieties: optical and electrochemical properties},
journal = {Mendeleev Communications},
year = {2018},
volume = {29},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.01.014},
number = {1},
pages = {47--49},
doi = {10.1016/j.mencom.2019.01.014}
}
MLA
Cite this
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Komissarova, Ekaterina Andreevna, et al. “Novel 2-alkoxy- and 2-alkylthio-substituted pyrimidines containing 2-(1-methyl-1H-pyrrol-2-yl)vinyl moieties: optical and electrochemical properties.” Mendeleev Communications, vol. 29, no. 1, Dec. 2018, pp. 47-49. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.01.014.

Abstract

A series of novel Y-shaped dyes bearing the D–π–A–π–D fragment comprising central 2-alkoxy-or 2-alkylthio-substituted pyrimidine core and terminal 2-(1-methyl-1H-pyrrol-2-yl)vinyl moieties have been synthesized and studied as potential materials for the organic electronics. The obtained compounds demonstrated an efficient absorption at ∼410nm with the high molar absorption coefficient (29790–40620 dm3 mol−1 cm−1) and fluorescence emission at ∼480nm (ΦF ∼ 7.5–8.6%). Thin films of 2-ethyloxy- or 2-ethylthiopyrimidines exhibited the red-shifted photoluminescence (∼600nm).

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