Home / Publications / Crystal structure and nontrivial magnetic properties of CuII binuclear complex based on 4-methyl-2,6-bis{[2-(4,6-dimethyl-pyrimidin-2-yl)hydrazono]methyl}phenol

Crystal structure and nontrivial magnetic properties of CuII binuclear complex based on 4-methyl-2,6-bis{[2-(4,6-dimethyl-pyrimidin-2-yl)hydrazono]methyl}phenol

Vladimir Viktorovich Lukov 1
Vladimir Viktorovich Lukov
, 
Arshak Aslanovich Tsaturyan 2
Arshak Aslanovich Tsaturyan
, 
Yulia Pavlovna Tupolova 1
Yulia Pavlovna Tupolova
, 
Sergei Ivanovich Levchenkov 1, 3
Sergei Ivanovich Levchenkov
, 
Valery Grigorievich Vlasenko 4
Valery Grigorievich Vlasenko
, 
Leonid Dmitrievich Popov 1
Leonid Dmitrievich Popov
, 
Ilia Vladimirovich Pankov 1
Ilia Vladimirovich Pankov
, 
Jordan C Poler 5
Jordan C Poler
10.1016/j.mencom.2019.01.013
Published 2018-12-28
Communication , Volume 29, Issue 1, 43-46
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Lukov V. V. et al. Crystal structure and nontrivial magnetic properties of CuII binuclear complex based on 4-methyl-2,6-bis{[2-(4,6-dimethyl-pyrimidin-2-yl)hydrazono]methyl}phenol // Mendeleev Communications. 2018. Vol. 29. No. 1. pp. 43-46.
GOST all authors (up to 50) Copy
Lukov V. V., Tsaturyan A. A., Tupolova Y. P., Levchenkov S. I., Vlasenko V. G., Popov L. D., Pankov I. V., Poler J. C. Crystal structure and nontrivial magnetic properties of CuII binuclear complex based on 4-methyl-2,6-bis{[2-(4,6-dimethyl-pyrimidin-2-yl)hydrazono]methyl}phenol // Mendeleev Communications. 2018. Vol. 29. No. 1. pp. 43-46.
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TY - JOUR
DO - 10.1016/j.mencom.2019.01.013
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.01.013
TI - Crystal structure and nontrivial magnetic properties of CuII binuclear complex based on 4-methyl-2,6-bis{[2-(4,6-dimethyl-pyrimidin-2-yl)hydrazono]methyl}phenol
T2 - Mendeleev Communications
AU - Lukov, Vladimir Viktorovich
AU - Tsaturyan, Arshak Aslanovich
AU - Tupolova, Yulia Pavlovna
AU - Levchenkov, Sergei Ivanovich
AU - Vlasenko, Valery Grigorievich
AU - Popov, Leonid Dmitrievich
AU - Pankov, Ilia Vladimirovich
AU - Poler, Jordan C
PY - 2018
DA - 2018/12/28
PB - Mendeleev Communications
SP - 43-46
IS - 1
VL - 29
ER -
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@article{2018_Lukov,
author = {Vladimir Viktorovich Lukov and Arshak Aslanovich Tsaturyan and Yulia Pavlovna Tupolova and Sergei Ivanovich Levchenkov and Valery Grigorievich Vlasenko and Leonid Dmitrievich Popov and Ilia Vladimirovich Pankov and Jordan C Poler},
title = {Crystal structure and nontrivial magnetic properties of CuII binuclear complex based on 4-methyl-2,6-bis{[2-(4,6-dimethyl-pyrimidin-2-yl)hydrazono]methyl}phenol},
journal = {Mendeleev Communications},
year = {2018},
volume = {29},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.01.013},
number = {1},
pages = {43--46},
doi = {10.1016/j.mencom.2019.01.013}
}
MLA
Cite this
MLA Copy
Lukov, Vladimir Viktorovich, et al. “Crystal structure and nontrivial magnetic properties of CuII binuclear complex based on 4-methyl-2,6-bis{[2-(4,6-dimethyl-pyrimidin-2-yl)hydrazono]methyl}phenol.” Mendeleev Communications, vol. 29, no. 1, Dec. 2018, pp. 43-46. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.01.013.

Abstract

The new complex [Cu2(H2L)Cl3] with axial chloride ions coordination based on 4-methyl-2,6-bis{[2-(4,6-dimethyl-pyrimidin-2-yl)hydrazono]methyl}phenol was obtained and its crystal structure was determined. Magnetic studies revealed the presence of antiferromagnetic exchange interaction of −193 cm−1 that is extremely high for such type of complexes. The quantum chemical calculation of 2J value has perfectly matched an experiment.

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