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Unusual iodination of arylsulfonylallenes

Stanislav Vasilyvich Lozovskiy 1
Stanislav Vasilyvich Lozovskiy
, 
Aleksandr Viktorovich Vasilyev 1, 2
Aleksandr Viktorovich Vasilyev
10.1016/j.mencom.2019.01.005
Published 2018-12-28
Communication , Volume 29, Issue 1, 19-21
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Lozovskiy S. V., Vasilyev A. V. Unusual iodination of arylsulfonylallenes // Mendeleev Communications. 2018. Vol. 29. No. 1. pp. 19-21.
GOST all authors (up to 50) Copy
Lozovskiy S. V., Vasilyev A. V. Unusual iodination of arylsulfonylallenes // Mendeleev Communications. 2018. Vol. 29. No. 1. pp. 19-21.
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TY - JOUR
DO - 10.1016/j.mencom.2019.01.005
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.01.005
TI - Unusual iodination of arylsulfonylallenes
T2 - Mendeleev Communications
AU - Lozovskiy, Stanislav Vasilyvich
AU - Vasilyev, Aleksandr Viktorovich
PY - 2018
DA - 2018/12/28
PB - Mendeleev Communications
SP - 19-21
IS - 1
VL - 29
ER -
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@article{2018_Lozovskiy,
author = {Stanislav Vasilyvich Lozovskiy and Aleksandr Viktorovich Vasilyev},
title = {Unusual iodination of arylsulfonylallenes},
journal = {Mendeleev Communications},
year = {2018},
volume = {29},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.01.005},
number = {1},
pages = {19--21},
doi = {10.1016/j.mencom.2019.01.005}
}
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Lozovskiy, Stanislav Vasilyvich, and Aleksandr Viktorovich Vasilyev. “Unusual iodination of arylsulfonylallenes.” Mendeleev Communications, vol. 29, no. 1, Dec. 2018, pp. 19-21. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.01.005.

Abstract

Arysulfonylallenes (ArSO2–CR1=C=CR2R3), depending on their structure, react with iodine to give two types of products, diiodo alkenes ArSO2–CHI–CI=CR2R3, when R1=H, or iodo dienes ArSO2–CR1=CI–C(Me)=CH2, when R1=Br, Ph and R2=R3=Me, in yields of 55–98%. The plausible reaction mechanisms have been proposed.

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